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Features of catalysis in the reaction of polyfluoroalkyl chlorosulfites with saturated monohydric alcohols

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Abstract

Synthetic opportunities and mechanism of catalysis of the reaction of polyfluororalkylchlorosulfites with saturated monohydric alcohols are considered. Kinetic measurements and quantum-chemical calculations showed that polyfluoroalkylation of these compounds proceeded through the step of complex formation involving reagents and catalyst followed by liberation of hydrogen chloride and sulfur dioxide and formation of polyfluoroalkyl ethers.

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References

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Authors and Affiliations

  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia

    A. I. Rakhimov & A. V. Nalesnaya

  2. Institute of Chemical Problems of Ecology, Russian Academy of Natural Sciences, Volgograd, Russia

    R. V. Fisechko

Authors
  1. A. I. Rakhimov
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  2. A. V. Nalesnaya
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  3. R. V. Fisechko
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Correspondence to A. I. Rakhimov.

Additional information

Original Russian Text © A.I. Rakhimov, A.V. Nalesnaya, R.V. Fisechko, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 11, pp. 1842–1848.

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Rakhimov, A.I., Nalesnaya, A.V. & Fisechko, R.V. Features of catalysis in the reaction of polyfluoroalkyl chlorosulfites with saturated monohydric alcohols. Russ J Gen Chem 78, 2075–2081 (2008). https://doi.org/10.1134/S1070363208110169

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  • DOI: https://doi.org/10.1134/S1070363208110169

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