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Micellar catalysis in the systems arylamine-diphenylamine-NO −2

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Abstract

By methods of UV and IR spectroscopy and thermogravimetry reactions of diazotizaion and azo coupling were studied in the systems of primary arylamine (p-nitro-, p-carboxy- and p-sulfoaniline)- diphenylamine -nitrite ion in water and micellar media on the basis of surfactants. The micellar catalysis effect of sodium dodecylsulfate in the micellar media was revealed. Rate of diazotization was shown to be independent of the surfactants of various types. Formation of ionic associates of azo dyes with dodecylsulfate anions in premicellar region was established and physicochemical characteristics of the associates were estimated.

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  1. Chernyshevskii Saratov State University, ul. Astrakhanskaya 83, Saratov, 410026, Russia

    S. Yu. Doronin & R. K. Chernova

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  1. S. Yu. Doronin
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  2. R. K. Chernova
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Original Russian Text © S.Yu. Doronin, R.K. Chernova, 2008, published in Zhurnal Obshchei Khimii, 2008, vol. 78, no. 11, pp. 1783–1788.

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Doronin, S.Y., Chernova, R.K. Micellar catalysis in the systems arylamine-diphenylamine-NO −2 . Russ J Gen Chem 78, 2019–2024 (2008). https://doi.org/10.1134/S1070363208110066

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  • DOI: https://doi.org/10.1134/S1070363208110066

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