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The first example of cobalt(III) μ-oxoacetate with water molecules in apical positions

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Abstract

Oxidation of Co(MeCOO)2·4H2O with ozone in acetic acid followed by the treatment with nitric acid results in the formation of the trinuclear oxo-centered acetate complex [CoIII 3(μ3-O)(μ-O2CMe)6(OH2)3] NO3·MeCOOH ([I]NO3·MeCOOH). Reasons of a decrease in the idealized symmetry of molecular structure (D 3h → D 3) of the complex cation [I]+ were analyzed by means of quantum-chemical calculations. The complex does not retain its structure in solutions (in water, methanol, and ethanol).

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Moskovskii pr. 26, St. Petersburg, 190013, Russia

    A. I. Fisher, D. O. Ruzanov, N. S. Panina, A. N. Belyaev & S. A. Simanova

  2. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, Moscow, Russia

    F. M. Dolgushin

  3. Umeo University, Umea, Sweden

    A. V. Shchukarev

Authors
  1. A. I. Fisher
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  2. D. O. Ruzanov
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  3. N. S. Panina
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  4. A. N. Belyaev
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  5. S. A. Simanova
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  6. F. M. Dolgushin
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  7. A. V. Shchukarev
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Correspondence to A. I. Fisher.

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Original Russian Text © A.I. Fisher, D.O. Ruzanov, N.S. Panina, A.N. Belyaev, S.A. Simanova, F.M. Dolgushin, A.V. Shchukarev, 2008, published in Zhurnal Obshchei Khimii, 2008, vol. 78, No. 11, pp. 1770–1776.

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Fisher, A.I., Ruzanov, D.O., Panina, N.S. et al. The first example of cobalt(III) μ-oxoacetate with water molecules in apical positions. Russ J Gen Chem 78, 2006–2012 (2008). https://doi.org/10.1134/S1070363208110042

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  • DOI: https://doi.org/10.1134/S1070363208110042

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