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Reaction of [Pt(NH3)4]Cl2·H2O and NH4ReO4 in alkaline aqueous solution at 190°C (under pressure)

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Abstract

Reactions of thermolysis under pressure of tetraammineplatinum(II) chloride and ammonium perrhenate in alkaline aqueous solution were studied. The products formed at the thermolysis in a pressure reactor were investigated. A model of platinum and rhenium ions reduction to metallic state by inner sphere ammonia from [Pt(NH3)4]Cl2 is suggested.

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Authors and Affiliations

  1. Korolev Samara State Aerocosmic University, Moskovskoe sh. 34, Samara, 443086, Russia

    V. I. Zarazhevskii, V. V. Grebnev, E. F. Fesik & G. D. Mal’chikov

Authors
  1. V. I. Zarazhevskii
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  2. V. V. Grebnev
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  3. E. F. Fesik
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  4. G. D. Mal’chikov
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Correspondence to G. D. Mal’chikov.

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Original Russian Text © V.I. Zarazhevskii, V.V. Grebnev, E.F. Fesik, G.D. Mal’chikov, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 11, pp. 1761–1763.

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Zarazhevskii, V.I., Grebnev, V.V., Fesik, E.F. et al. Reaction of [Pt(NH3)4]Cl2·H2O and NH4ReO4 in alkaline aqueous solution at 190°C (under pressure). Russ J Gen Chem 78, 1997–1999 (2008). https://doi.org/10.1134/S1070363208110017

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  • DOI: https://doi.org/10.1134/S1070363208110017

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