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Synthesis and magnetic properties of quasi-unidimensional oxide Sr6.3Rh2.35Mn2.35O15

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Abstract

Attempts of the synthesis in air of complex oxides Sr3RhMnOx and Sr4Rh1.5Mn1.5Ox resulted in revealing formation of a new oxide phase Sr6.3Rh2.35Mn2.35O9 related to quasi-unidimensional family A3n+3m A′ n B3m+n O9m+6n at n = 1 and m = 1. Its structural characteristics and magnetic properties are studied. X-ray data of the obtained phase is indicated on the basis of trigonal cell (spatial group P321) with the parameters: a 9.6239(4) Å; c 1 4.1130(4) Å, c 2 2.4946(2) Å. Manganese and rhodium exist in the compound as the cations Mn4+, Rh3+ and Rh4+, as follows from the data of measuring of magnetic susceptibility in the range 2–300 K.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Ykaterinburg, 620041, Russia

    G. V. Bazuev, T. I. Chupakhina & M. A. Lelkozerova

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  1. G. V. Bazuev
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  2. T. I. Chupakhina
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  3. M. A. Lelkozerova
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Correspondence to G. V. Bazuev.

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Original Russian Text © G.V. Bazuev, T.I. Chupakhina, M.A. Lelkozerova, 2008, published in Zhurnal Obshchei Khimii, 2008, vol. 78, No. 10, pp. 1605–1610.

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Bazuev, G.V., Chupakhina, T.I. & Lelkozerova, M.A. Synthesis and magnetic properties of quasi-unidimensional oxide Sr6.3Rh2.35Mn2.35O15 . Russ J Gen Chem 78, 1843–1848 (2008). https://doi.org/10.1134/S1070363208100034

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  • DOI: https://doi.org/10.1134/S1070363208100034

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