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Synthesis and spectral properties of [3-(heptyloxy)phenoxy]acetic acid and its derived meso-sibstituted tetrabenzoporphyrins

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Abstract

3-Heptyloxyphenol was obtained by reaction of resorcinol with 1-bromoheptane. Further alkylation with monochloroacetc acid resulted in the synthesis of [3-(heptyloxy)phenoxy]acetic acid. Heating of the latter with phthalimide in the presence of zinc acetate afforded zinc complexes of meso-[(3-heptyloxy)phenoxy] tetrabenzoporphyrins whose demetalization gave free porphyrin bases. Spectral properties of the synthesized compounds were studied.

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Authors and Affiliations

  1. Ivanovo State Chemical Technological University, pr. F. Engel’sa 7, Ivanovo, 153000, Russia

    N. E. Galanin, L. A. Yakubov & G. P. Shaposhnikov

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  1. N. E. Galanin
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  2. L. A. Yakubov
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  3. G. P. Shaposhnikov
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Correspondence to N. E. Galanin.

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Original Russian Text © N.E. Galanin, L.A. Yakubov, G.P. Shaposhnikov, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 9, pp. 1572–1577.

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Galanin, N.E., Yakubov, L.A. & Shaposhnikov, G.P. Synthesis and spectral properties of [3-(heptyloxy)phenoxy]acetic acid and its derived meso-sibstituted tetrabenzoporphyrins. Russ J Gen Chem 78, 1802–1807 (2008). https://doi.org/10.1134/S1070363208090259

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  • DOI: https://doi.org/10.1134/S1070363208090259

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