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Phthalocyanines and related compounds: XLVIII. Stepwise nucleophilic substitution in tetrachlorophthalonitrile: Synthesis of polysubstituted phthalonitriles

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Abstract

Chlorine-containing products of incomplete nucleophilic substitution in tetrachlorophthalonitrile were subjected to further reaction with nucleophiles. The nature of the nucleophiles and the order of their introduction into stepwise nucleophilic substitution in tetrachlorophthalonitrile were shown to be of principal importance for selective synthesis on this basis of phthalonitrile derivatives with various substituents.

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Authors and Affiliations

  1. Scientific Research Institute of Organic Intermediates and Dyes, ul. Bol’shaya Sadovaya 1/4, Moscow, 123995, Russia

    K. A. Volkov, V. M. Negrimovskii & E. A. Luk’yanets

  2. Mendeleev Russian University of Chemical Technology, Moscow, Russia

    G. V. Avramenko

Authors
  1. K. A. Volkov
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  2. V. M. Negrimovskii
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  3. G. V. Avramenko
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  4. E. A. Luk’yanets
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Correspondence to K. A. Volkov.

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Original Russian Text © K.A. Volkov, V.M. Negrimovskii, G.V. Avramenko, E.A. Luk’yanets, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 9, pp. 1564–1571.

For communication XLVII, see [1].

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Volkov, K.A., Negrimovskii, V.M., Avramenko, G.V. et al. Phthalocyanines and related compounds: XLVIII. Stepwise nucleophilic substitution in tetrachlorophthalonitrile: Synthesis of polysubstituted phthalonitriles. Russ J Gen Chem 78, 1794–1801 (2008). https://doi.org/10.1134/S1070363208090247

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  • DOI: https://doi.org/10.1134/S1070363208090247

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