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Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system

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Abstract

Methods of synthesis of compounds MeY(CH2Y) n Me (Y=S, Se, Te; n = 1–3) containing several identical or different chalcogen atoms are suggested. The methods are based on the reactions of dichloromethane with elemental chalcogens (Y2−) and dimethyl dichalcogenides (MeY−) activated in the system hydrazine hydrate-alkali. The effect of the chalcogen on the reactivity toward dichloromethane is qualitatively assessed. With elemental tellurium in the system hydrazine hydrate-alkali, reduction of one chlorine atom in dichloromethane and formation of methyltellanyl derivatives are observed.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    E. P. Levanova, V. Yu. Vshivtsev, E. N. Sukhomazova, V. A. Grabel’nykh, N. V. Russavskaya, E. R. Zhanchipova, L. V. Klyba, A. I. Albanov & N. A. Korchevin

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  1. E. P. Levanova
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  2. V. Yu. Vshivtsev
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  3. E. N. Sukhomazova
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  4. V. A. Grabel’nykh
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  5. N. V. Russavskaya
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  6. E. R. Zhanchipova
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  7. L. V. Klyba
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  8. A. I. Albanov
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  9. N. A. Korchevin
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Correspondence to E. P. Levanova.

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Original Russian Text © E.P. Levanova, V.Yu. Vshivtsev, E.N. Sukhomazova, V.A. Grabel’nykh, N.V. Russavskaya, E.R. Zhanchipova, L.V. Klyba, A.I. Albanov, N.A. Korchevin, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 9, pp. 1502–1510.

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Levanova, E.P., Vshivtsev, V.Y., Sukhomazova, E.N. et al. Reactions of dichloromethane with chalcogens and dimethyl chalcogenides in the hydrazine hydrate-alkali system. Russ J Gen Chem 78, 1734–1741 (2008). https://doi.org/10.1134/S1070363208090156

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  • DOI: https://doi.org/10.1134/S1070363208090156

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