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Synthesis and spectral parameters of tetra(6-tert-butyl-2,3-quinoxalino)porphyrazine and its metal complexes

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Abstract

Tetra(6-tert-butyl-2,3-quinoxalino)porphyrazine and its complexes with bivalent metals were synthesized for the first time by template tetramerization of 6-tert-butylquinoxaline-2,3-dicarbonitrile. The obtained macrocyclic compounds are soluble in hydrophobic solvents. Their electronic absorption spectra in organic solvents and the spectra of the corresponding protonated forms in sulfuric acid were studied.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, pr. F. Engel’sa 7, Ivanovo, 153000, Russia

    S. V. Efimova

  2. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    A. B. Korzhenevskii & O. I. Koifman

Authors
  1. S. V. Efimova
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  2. A. B. Korzhenevskii
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  3. O. I. Koifman
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Corresponding author

Correspondence to S. V. Efimova.

Additional information

Original Russian Text © S.V. Efimova, A.B. Korzhenevskii, O.I. Koifman, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 7, pp. 1214–1218.

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Efimova, S.V., Korzhenevskii, A.B. & Koifman, O.I. Synthesis and spectral parameters of tetra(6-tert-butyl-2,3-quinoxalino)porphyrazine and its metal complexes. Russ J Gen Chem 78, 1447–1451 (2008). https://doi.org/10.1134/S1070363208070293

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  • DOI: https://doi.org/10.1134/S1070363208070293

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