Abstract
Annealing in reducing atmosphere allows stabilization of the Sn4+, Sb5+, or Te6+ dopant cations in a lower oxidation state. Due to its stereochemical activity, the lone electron pair of the resulting Sn2+, Sb3+, or Te4+ favors the location of these species in low-coordination sites, immediately on the surface of the substrate-compound crystallites. This allows 119Sn, 121Sb, or 125Te Møssbauer spectroscopy to be applied for studying the processes occurring at the solid-gas interface. Results of such studies, mainly devoted to the Cr2O3 antiferromagnetic substrate, were discussed, along with the prospects of searching appropriate substrate-compounds of other types.
Similar content being viewed by others
References
Fabrichnyi, P.B., Protskii, A.N., Gor’kov, V.P., et al., Zh. Eks. Teor. Fiz., 1981, vol. 81, no. 3, p. 1145.
Fabrichnyi, P.B., Zh. Vses. Khim. O-va. im. D.I. Mendeleeva, 1985, vol. 30, no. 2, p. 143.
Afanasov, M.I. and Fabrichnyi, P.B., Ross. Khim. Zh. (Zh. Ross. Khim. O-va. im. D.I. Mendeleeva), 1996, vol. 40, no. 1, p. 54.
Afanasov, M.I., Korolenko, M.V., Danot, M., and Fabritchnyi, P.B., Solid State Commun., 2002, vol. 124, p. 407.
Afanasov, M.I., Ryabchikov, A.A., Korolenko, M.V., et al., Izv. Ross. Akad. Nauk, Ser. Fiz., 2001, vol. 65, no. 7, p. 1035.
Foner, S., J. Phys. Radium, 1949, vol. 20, p. 336.
Danot, M., Afanasov, M.I., Bezverkhy, I.S., et al., Solid State Commun., 1994, vol. 91, no. 9, p. 675.
Afanasov, M.I., Danot, M., Ryabchikov, A.A., et al., Mater. Res. Bull., 1996, vol. 31, no. 5, p. 465.
Fabritchnyi, P.B., Afanasov, M.I., Danot, M., et al., Solid State Commun., 1997, vol. 102, no. 10, p. 749.
Afanasov, M.I., Bezverkhii, I.S., Fabrichnyi, P.B., and Danot, M., Zh. Neorg. Khim., 2001, vol. 46, no. 12, p. 2056.
Shannon, R.D. and Prewitt, C.T., Acta Cryst. Sect. B, 1969, vol. 25, p. 925.
Bezverkhy, I.S., Afanasov, M.I., Fabritchnyi, P.B., et al., J. Radioanal. Nucl. Chem., 1998, vol. 232, nos. 1–2, p. 241.
Afanasov, M.I., Bezverkhii, I.S., Kolotyrkina, M.A., et al., Zh. Neorg. Khim., 2000, vol. 45, no. 6, p. 1016.
Fabritchnyi, P.B., Afanasov, M.I., Bezverkhy, I.S., and Danot, M., J. Solid State Chem., 2001, vol. 162, p. 293.
Legasov, V., Fabritchnyi, P., Demazeau, G., et al., Comptes Rendus Acad. Sci. (Paris), 1988, vol. 306, no. 2, p. 879.
Danot, M., Afanasov, M.I., Ryabchikov, A.A., et al., Solid State Commun., 1996, vol. 99, no. 4, p. 249.
Danot, M., Afanasov, M.I., Ryabchikov, A.A., et al., J. Solid State Chem., 1997, vol. 132, p. 284.
Herber, R.H., Smelkinson, A.E., Sienko, M.J., and Schneemeyer, L.F., J. Chem. Phys., 1978, vol. 68, p. 3705.
Fournés, L., Grannec, J., and Potin, Y., Hyperfine Interactions, 1990, vol. 55, p. 1137.
Karyagin, S.V., Dokl. Akad. Nauk SSSR, 1963, vol. 148, p. 1102.
Miyamoto, A., Ui, T., and Murakami, Y., J. Catal., 1983, vol. 80, p. 106.
Fabritchnyi, P.B., Sudakova, N.R., Berentsveig, V.V., et al., J. Mater. Chem., 1992, vol. 2, no. 7, p. 763.
Fabritchnyi, P.B., Sudakova, N.R., Gorkov, V.P., et al., Mater. Res. Bull., 1993, vol. 28, no. 2, p. 179.
Morozova, N.I., Kulakova, I.I., Afanasov, M.I., et al., Abstarct of Papers, 2d Int. Conf. “Highly-Organized Catalytic Systems”, Moscow, June 14–17, 2004, p. 94.
Morozova, N.I., Kulakova, I.I., Afanasov, M.I., et al., Kinet. Kataliz, 2005, vol. 46, no. 3, p. 406.
Morozova, N.I., Kulakova, I.I., Afanasov, M.I., et al., Abstract of Papers, 2d Int. Conf. “Highly-Organized Catalytic Systems”, Moscow, June 14–17, 2004, p. 93.
Morozova, N.I., Kulakova, I.I., Afanasov, M.I., and Fabrichnyi, P.B., Vestn. Mosk. Univ., Ser. Khim., 2006, vol. 47, no. 5, p. 353.
Fabritchnyi, P.B. and Fefilatiev, L.P., Solid State Commun., 1978, vol. 28, p. 513.
Fefilatiev, L.P., Demazeau, G., Fabritchnyi, P.B., and Babechkin, A.M., Solid State Commun., 1978, vol. 28, p. 509.
Fabritchnyi, P.B., Kuzmin, A.I., Khaskov, A.V., and Babechkin, A.M., Solid State Commun., 1974, vol. 15, p. 783.
Fabrichnyi, P.B., Babeshkin, A.M., Nesmeyanov, A.N., and Onuchak, V.N., Fiz. Tverd. Tela, 1970, vol. 12, no. 7, p. 2032.
Fabritchnyi, P.B., Lamykin, E.B., Babechkin, A.M., and Nesmeianov, A.N., Solid State Commun., 1972, vol. 11, no. 2, p. 343.
Jiang, J.Z., Lin, R., Lin, W., et al., J. Phys. D: Appl. Phys., 1997, vol. 30, p. 1459.
Berry, F.J., Bohörquez, A., Helgason, Ö., et al., J. Phys.: Condens. Matter., 2000, vol. 12, p. 4043.
Kovalenko, V.V., Rumyantseva, M.N., Fabritchnyi, P.B., and Gaskov, A.M., Mendeleev Commun., 2004, p. 140.
Fabritchny, P.B., Korolenko, M.V., Afanasov, M.I., and Danot, M., Solid State Commun., 2003, vol. 125, p. 341.
Korolenko, M.V., Danot, M., Fabrichnyi, P.B., et al., Zh. Neorg. Khim., 2005, vol. 50, no. 8, p. 1344.
Fabrichnyi, P.B., Lamykin, E.V., Babeshkin, A.M., and Nesmeyanov, A.N., Fiz. Tverd. Tela, 1971, vol. 13, no. 11, p. 3417.
Afanasov, M.I., Fabrichnyi, P.B., Korolenko, M.V., and Ivanova, T.M., Zh. Neorg. Khim., 2008, vol. 53 (in press).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © P.B. Fabrichnyi, M.I. Afanasov, M. Danot, 2008, published in Rossiiskii Khimicheskii Zhurnal, 2007, Vol. 51, No. 6, pp. 44–51.
Rights and permissions
About this article
Cite this article
Fabrichnyi, P.B., Afanasov, M.I. & Danot, M. 5s5p element dopant cations: Møssbauer probes for studying chemical reactions at the solid-gas interface. Russ J Gen Chem 78, 1060–1069 (2008). https://doi.org/10.1134/S1070363208050393
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363208050393