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5s5p element dopant cations: Møssbauer probes for studying chemical reactions at the solid-gas interface

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Abstract

Annealing in reducing atmosphere allows stabilization of the Sn4+, Sb5+, or Te6+ dopant cations in a lower oxidation state. Due to its stereochemical activity, the lone electron pair of the resulting Sn2+, Sb3+, or Te4+ favors the location of these species in low-coordination sites, immediately on the surface of the substrate-compound crystallites. This allows 119Sn, 121Sb, or 125Te Møssbauer spectroscopy to be applied for studying the processes occurring at the solid-gas interface. Results of such studies, mainly devoted to the Cr2O3 antiferromagnetic substrate, were discussed, along with the prospects of searching appropriate substrate-compounds of other types.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Vorob’evy gory 1, Moscow, 119992, Russia

    P. B. Fabrichnyi & M. I. Afanasov

  2. J. Rouxel Institut des Materiaux de Nantes, Centre National de la Recherche Scientifique, Nantes, France

    M. Danot

Authors
  1. P. B. Fabrichnyi
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  2. M. I. Afanasov
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  3. M. Danot
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Correspondence to P. B. Fabrichnyi.

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Original Russian Text © P.B. Fabrichnyi, M.I. Afanasov, M. Danot, 2008, published in Rossiiskii Khimicheskii Zhurnal, 2007, Vol. 51, No. 6, pp. 44–51.

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Fabrichnyi, P.B., Afanasov, M.I. & Danot, M. 5s5p element dopant cations: Møssbauer probes for studying chemical reactions at the solid-gas interface. Russ J Gen Chem 78, 1060–1069 (2008). https://doi.org/10.1134/S1070363208050393

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