Abstract
Investigation of the reaction of some vinylsilanes of the general formula Cl3−n (CH3) n SiCH=CH2 (n = 0,1,2,3) and 1,2-bis(trimethylsilyl)ethylene with trimethylgermane and trichlorogermane etherate was carried out. It was established that hydrogermylation only at the use of HGeCl3·2Et2O was sensitive to the nature of the substituting silyl groups in vinylsilanes. Nucleophilic mechanism of the reaction of trichlorogermane etherate with vinylsilanes is suggested.
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Petrov, A.D., Mironov, V.F., and Jurinskaya, N.G., Dokl. Akad. Nauk SSSR, 1959, vol. 128, no. 2, p. 302.
Mironov, V.F., Jurinskaya, N.G., Gar, T.K., and Petrov, A.D., Izv. Akad. Nauk SSSR, Otd. Khim. Nauk. 1962, no. 3, p. 460.
Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Zakrzewski, V.G., Montgomery, J.A., Stratmann, R.E., Buran J.C., Dapprich, S., Millam, J.M., Daniels, A.D., Kudin, K.N., Strain, M.C., Farkas, O., Tomasi, J., Barone, V., Cossi, M., Cammi, R., Mennucci, B., Pomelli, C., Adamo, C., Clifford, S., Ochterski, J., Petersson, G.A., Ayala, P.Y., Cui, Q., Morokuma, K., Malick, D.K., Rabuck, A.D., Raghavachari, K., Foresman, J.B., Cioslowski, J., Ortiz, J.V., Baboul, A.G., Stefanov, B.B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Gomperts, R., Martin, R.L., Fox, D.J., Keith, T., Al-Laham, M.A., Peng, C.Y., Nanayakkara, A., Challacombe, M., Gill, P.M.W., Johnson, B., Chew, W., Wong, M.W., Anders, J.L., Gonzalez, C., Head-Gordon, M., Replogle, E.S., and Pople, J.A., Gaussian 98, Rev. A.7, Pittsburg: Gaussian, 1998.
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Original Russian Text © V.G. Lakhtin, S.P. Knyazev, K.V. Pavlov, L.E. Gusel’nikov, E.N. Buravtseva, N.A. Kuyantseva, L.A. Parshkova, A.A. Mid’ko, V.G. Bykovchenko, A.V. Kisin, E.A. Chemyshev, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 5, pp. 756–760.
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Lakhtin, V.G., Knyazev, S.P., Pavlov, K.V. et al. Hydrogermylation of silyl-substituted ethylenes with trimethylgermane and trichlorogermane etherate. Russ J Gen Chem 78, 898–902 (2008). https://doi.org/10.1134/S1070363208050101
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DOI: https://doi.org/10.1134/S1070363208050101