Abstract
Phosphorylation of β-cyclodextin with substituted secondary hydroxy groups using 1,2-O,O′-isopropylideneglyceryl phosphorous diamide as a phosphorylating agent, in contrast to phosphorylation with trivalent phosphorus acid chlorides, is found to proceeds under mild conditions, but only in homogenous medium, and to afford acyclic diesteroamidophosphite derivatives of β-cyclodextin.
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Original Russian Text © G.I. Kurochkina, I.A. Senyushkina, M.K. Grachev, E.E. Nifant’ev, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 5, pp. 738–740.
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Kurochkina, G.I., Senyushkina, I.A., Grachev, M.K. et al. Phosphorylation of β-cyclodextrin with substituted secondary hydroxy groups using phosphorous acid diamide. Russ J Gen Chem 78, 880–882 (2008). https://doi.org/10.1134/S1070363208050071
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DOI: https://doi.org/10.1134/S1070363208050071