Skip to main content
SpringerLink
Log in

Ionic equilibria in alkaline aqueous solutions of metal complex salts

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

A thermodynamic analysis of the formation conditions of metal hydroxides was performed. The areas of stable formation of metal hydroxide precipitates in the coordinates pH-metal concentration, including also solutions containing various kinds of complexing agents, were evaluated. With the precipitation of cadmium hydroxide as example, X-ray phase analysis confirmed the formation of metal hydroxide in the chemical composition areas where its formation is predicted by a thermodynamic analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rempel’, A.A., Usp. Khim., 2007, vol. 76, no. 5, p. 474.

    Google Scholar 

  2. Uritskaya, A.A., Bol’shchikova, T.P., and Kozhevnikova, N.S., Zh. Obshch. Khim., 2007, vol. 77, no. 5, p. 717.

    Google Scholar 

  3. Kozhevnikova, N.S., Rempel’, A.A., Hergert, F., and Magerl, F., Zh. Fiz. Khim., 2007, vol. 81, no. 5, p. 768.

    CAS  Google Scholar 

  4. Rempel, A.A., Kozhevnikova, N.S., Van den Berghe, S., Van Renterghem, W., and Leenaers, A.J.G., Phys. Status Solidi, 2005, vol. 242, no. 7, p. R61.

    Article  CAS  Google Scholar 

  5. Kitaev, G.A., Bol’shchikova, T.P., Fofanov, G.M., Yatlova, L.E., and Goryukhina, N.M., in Kinetika i mekhanizm obrazovaniya tverdoi fazy (Kinetics and Mechanism of Solid Phase Formation), Sverdlovsk: Ural’sk. Politekh. Inst., 1968, p. 113.

    Google Scholar 

  6. Kitaev, G.A., Mokrushin, S.G., and Uritskaya, A.A., Kolloidn. Zh., 1965, vol. 27, no. 1, p. 51.

    CAS  Google Scholar 

  7. O’Brien, P. and Saeed, T., J. Crystal Growth, 1996, vol. 158, no. 4, p. 497.

    Article  CAS  Google Scholar 

  8. Butler, J.N., Ionic Equilibrium (A Mathematical Approach), Reading, Massachusetts: Addison-Wesley, 1964.

    Google Scholar 

  9. Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Leningrad: Khimiya, 1989.

    Google Scholar 

  10. Schwarzenbach, G. and Přibil, R., Komplexometrie, Prague: Chemapol, 1955. Translated under the title Kompleksonometriya, Moscow: Goskhimizdat, 1958, p. 5.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, GSP-145, Ul. Pervomaiskaya 91, Yekaterinburg, 620041, Russia

    N. S. Kozhevnikova, A. S. Vorokh & A. A. Rempel

  2. Ural State Technical University, Yekaterinburg, Russia

    N. S. Kozhevnikova, A. A. Uritskaya & A. A. Rempel

Authors
  1. N. S. Kozhevnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Uritskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Vorokh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Rempel
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. S. Kozhevnikova.

Additional information

Original Russian Text © N.S. Kozhevnikova, A.A. Uritskaya, A.S. Vorokh, A.A. Rempel’, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 4, pp. 568–573.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kozhevnikova, N.S., Uritskaya, A.A., Vorokh, A.S. et al. Ionic equilibria in alkaline aqueous solutions of metal complex salts. Russ J Gen Chem 78, 551–556 (2008). https://doi.org/10.1134/S1070363208040075

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363208040075

Keywords

Search

Navigation