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Proton-acceptor properties of azahomofullerene and fullerenoaziridine containing a cyanuric acid fragment

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Abstract

13C and 1H NMR and UV spectral studies on 1,3-diallyl-5-[4-(azahomo[60]fullereno)butyl]hexahydro-1,3,5-triazine-2,4,6-trione ([5,6]-open isomer) and 1,3-diallyl-5-[4-(aziridino[60]fullereno)butyl]hexahydro-1,3,5-triazine-2,4,6-trione ([6,6]-closed isomer), as well as quantum-chemical calculations, showed that only the latter possesses weakly basic properties.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    I. P. Romanova, O. A. Larionova, A. A. Balandina, Sh. K. Latypov, A. R. Mustafina, V. V. Skripacheva, V. V. Zverev & O. G. Sinyashin

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  1. I. P. Romanova
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  2. O. A. Larionova
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  3. A. A. Balandina
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  4. Sh. K. Latypov
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  5. A. R. Mustafina
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  6. V. V. Skripacheva
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  7. V. V. Zverev
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  8. O. G. Sinyashin
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Correspondence to I. P. Romanova.

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Original Russian Text © I.P. Romanova, O.A. Larionova, A.A. Balandina, Sh.K. Latypov, A.R. Mustafina, V.V. Skripacheva, V.V. Zverev, O.G. Sinyashin, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 3, pp. 466–471.

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Romanova, I.P., Larionova, O.A., Balandina, A.A. et al. Proton-acceptor properties of azahomofullerene and fullerenoaziridine containing a cyanuric acid fragment. Russ J Gen Chem 78, 451–456 (2008). https://doi.org/10.1134/S1070363208030201

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  • DOI: https://doi.org/10.1134/S1070363208030201

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