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Solvent effect on the reactivity of trichloromethylperoxy radicals

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Abstract

The solvent effect on the rate of reaction of organic reductants with trichloromethylperoxy radicals can be adequaetly described by multiparameter linear equations. The major factor affecting the reaction rate is the solvent cohesion, enhancing the cage effect.

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Authors and Affiliations

  1. Division of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Fuel Chemistry, National Academy of Sciences of Ukraine, ul. Nauchnaya 3a, Lviv, 79053, Ukraine

    G. G. Midyana

  2. Institute of Geology and Geochemistry of Fossil Fuels, National Academy of Sciences of Ukraine, Lviv, Ukraine

    R. G. Makitra & E. Ya. Pal’chikova

Authors
  1. G. G. Midyana
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  2. R. G. Makitra
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  3. E. Ya. Pal’chikova
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Correspondence to G. G. Midyana.

Additional information

Original Russian Text © G.G. Midyana, R.G. Makitra, E.Ya. Pal’chikova, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 3, pp. 454–456.

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Midyana, G.G., Makitra, R.G. & Pal’chikova, E.Y. Solvent effect on the reactivity of trichloromethylperoxy radicals. Russ J Gen Chem 78, 439–441 (2008). https://doi.org/10.1134/S1070363208030171

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  • DOI: https://doi.org/10.1134/S1070363208030171

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