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Correlation of the reactivity of organometallic chlorides in the oxidation of magnesium with the electronic structure of the organic moiety

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Abstract

From the linear correlation of the chemical shift (19F) in compounds R-C≡C-C6H4-F-p (reference PhF, solvent to-luene) with the Hammett σ p constants of substituents R, the σ p constants of organometallic substituents R [Cp(CO)3Mo, Cp(CO)3W, Cp(CO)2Fe, Cp(PPh3)Ni, Ph2Bi, Ph2Sb, Ph3Sn] were calculated. The logarithm of the rate constant of magnesium oxidation with compounds RCl linearly correlates with the σ p constants of the organometallic groups R.

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Authors and Affiliations

  1. Research Institute of Chemistry, Lobachevsky Nizhni Novgorod State University, pr. Gagarina 23, block 5, Nizhni Novgorod, 603950, Russia

    S. V. Panteleev, S. V. Maslennikov & V. P. Maslennikov

  2. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhni Novgorod, Russia

    A. N. Egorochkin

Authors
  1. S. V. Panteleev
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  2. S. V. Maslennikov
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  3. A. N. Egorochkin
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  4. V. P. Maslennikov
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Correspondence to S. V. Panteleev.

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Original Russian Text © S.V. Panteleev, S.V. Maslennikov, A.N. Egorochkin, V.P. Maslennikov, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 3, pp. 437–439.

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Panteleev, S.V., Maslennikov, S.V., Egorochkin, A.N. et al. Correlation of the reactivity of organometallic chlorides in the oxidation of magnesium with the electronic structure of the organic moiety. Russ J Gen Chem 78, 421–423 (2008). https://doi.org/10.1134/S1070363208030134

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  • DOI: https://doi.org/10.1134/S1070363208030134

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