Abstract
Kinetic studies and MP3 quantum-chemical calculations were used to show that the reactions of ε-caprolactam with phosphorodiamidous chloride and phosphorochloridites I–III involve nucleophilic substitution of the chlorine atom in the latter by a 2-oxoazepane residue.
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Original Russian Text © A.I. Rakhimov, E.A. Pugacheva, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 1, pp. 50–52.
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Rakhimov, A.I., Pugacheva, E.A. On the mechanism of reaction of ε-caprolactam with phosphorous chlorides. Russ J Gen Chem 78, 47–49 (2008). https://doi.org/10.1134/S1070363208010088
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DOI: https://doi.org/10.1134/S1070363208010088