Abstract
Properties of Ca-and Na-montmorillonites and their acid-activation products are studied by modern physicochemical methods. New evidence showing that the mechanism of acid activation of montmorillonites involves consecutive deactionation is presented. Features of formation and properties of the composite materials obtained on the basis of acid-activated montmorillonites and alumina are considered. It is shown that such materials hold promise as catalyst carriers and sorbents.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Syr’evaya baza bentonitov SSSR i ikh ispol’zovanie v narodnom khozyaistve (Bentonite Raw Materials in USSR and Their Application in National Economy), Moscow: Nedra, 1972.
Merabishvili, M.S., Bentonitovye gliny (Bentonite Clays), Leningrad: Gosgeoltekhizdat, 1962.
Grim, R., Mineralogiya i prakticheskoe ispol’zovanie glin, Moscow: Mir, 1967.
Kukovskii, E.G., Osobennosti stroeniya i fiziko-khimicheskie svoistva glinistyh mineralov (Structural Features and Physicochemical Properties of Clay Minerals), Kiev: Naukova Dumka, 1966.
Montes, H G., Duplay, J., Martinez, L., et al., Appl. Clay Sci., 2003, vol. 23, p. 309.
Distanov, U.G., Mikhailov, A.S., Konyukhova, T.P., et al., Prirodnye sorbenty SSSR (Naturals Sorbents in the USSR), Moscow: Nedra, 1990.
Battalova, Sh.B., Fiziko-khimicheskie osnovy polucheniya i primeneniya katalizatorov i adsorbentov iz bentonitov (Physicochemical Principles of Preparation and Application of Bentonite Catalysts and Adsorbents), Alma-Ata: Nauka, 1986.
Suzdalev, I.P., Nanotekhnologiya: fiziko-khimiya nanoklasterov, nanostruktur i nanomaterialov (Nanotechnology: Physical Chemistry of Nanoclusters, Nanostructures, and Nanomaterials), Moscow: KomKniga, 2006.
Ogenko, V.M., Dubrovina, L.V., and Lysyuk, L.S., Ukr. Khim. Zh., 2005, vol. 71, p. 16.
Shabanova, N.A., Popov, V.V., and Sarkisov, P.D., Kimiya i tekhnologiya nanodispersnyh oksidov (Chemistry and Technology of Nanodisperse Oxides), Moscow: Akademkniga, 2006.
Flessner, U., Roziere, D. J., Zajac, J., et al., J. Mol. Catal. A: Chem., 2001, vol. 168, p. 247.
Hart, M.P. and Brown, D.D., J. Mol. Catal. A, 2004, vol. 212, p. 315.
Moronta, A., Luengo, J., Ramirez, Y., et al., J. Appl. Clay Sci., 2005, vol. 29, p. 117.
Harrad, D., Chambellan, A., and Lavalley, J.C., Catal. Lett., 1998, vol. 54, p. 227.
Drozdov, V.A., Doronin, V.P., Sorokina, T.P., et al., Kinet. Katal., 2001, vol. 42, p. 129.
Tarasevich, Yu.I. and Ovcharenko, F.D., Adsorbenty, ikh poluchenie, svoistva i primenenie (Adsorbents, Their Preparation, Properties, and Application), Leningrad: Nauka, 1978.
Lapteva, E.S., Yusupov, T.S., and Berger, A.S., Fiziko-khimicheskie izmeneniya sloistyh silikatov v protsesse mekhanicheskoi aktivatsii (Physicochemical Changes in Lamellar Silicates in the Course of Mechanical Activation), Novosibirsk: Nauka, 1981.
Dudkin, B.N., Loukhina I.V., Avvakumov, E.G., and Isupov, V.P., Khim. Interesakh Ustoich. Razvitiya, 2004, vol. 12, p. 327.
Neaman, A., Pelletier, M., and Villieras, F., Appl. Clay Sci., 2003, vol. 22, p. 153.
Adams, J.M., Ibid., 1987, vol. 2, p. 309.
Gates, W.P., Anderson, J.S., Raven, M.D., and Churchman, G.J., Ibid., 2002, vol. 20, p. 189.
Colina, F.G. and Costa, J., Ind. Eng. Chem. Res., 2005, vol. 44, p. 4495.
Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Fundamentals of Adsorption Technics), Moscow: Khimiya, 1984.
Corma, A. and Garcia, H., Catal. Today, 1997, vol. 38, p. 257.
Okada, K., Arimitsu, N., Kameshima, Y., et al., Appl. Clay Sci., 2006, vol. 31, p. 185.
Kumar P., Jasra R.V., and Bhat, T.S.G., Ind. Eng. Chem. Res., 1995, vol. 34, p. 1440.
Okada, K., Arimitsu, N., Kameshima, Y., et al., Appl. Clay Sci., 2005, vol. 30, p. 116.
Murray, H.H., Clay Miner., 1999, vol. 34, p. 393.
Yadav, M.K., Chudasma, C.D., and Jasra, R.V., J. Mol. Catal. A: Chem., 2004, vol. 216, p. 519.
Mahmoud, S. and Saleh, S., Clays Clay Miner., 1999, vol. 47, p. 481.
Adams, J.M., Clapp, T.V., and Clement, D.E., Clay Miner., 1983, vol. 18, p. 411.
Tyagi, B., Chudasma, C.D., and Jasra, R.V., Ibid., 2006, vol. 31, p. 16.
Rhodes, C.N. and Brown, D.R., Catal. Lett., 1994, vol. 24, p. 285.
Tkac, I., Komadel, P., and Muller, D., Clay Miner., 1994, vol. 29, p. 11.
Gilinskaya, L.G., Grigor’eva, T.N., Razvorotneva, L.I., and Trofimova, L.B., Zh. Neorg. Khim., 2005, vol. 50, p. 689.
Mank, V.V., Karushkina, A.Ya., Ovcharenko, F.D., and Vasil’ev, N.G., Dokl. Akad. Nauk SSSR, 1974, vol. 218, p. 921.
Pentin, Yu.A. and Vilkov, L.V., Fizicheskie metody issledovaniya v khimii (Physical Methods of Investigation in Chemistry), Moscow: Mir, 2003, p. 683.
Dzis’ko, V.A., Karnaukhov, A.P., and Tarasova, D.V., Fiziko-khimicheskie osnovy sinteza okisnykh katalizatorov (Physicochemical Principles of Synthesis of Oxide Catalysts), Novosibirsk: Nauka, 1978.
Kaplan, F.S. and Pivinskii, Yu.E., in: Khimiya i tekhnologiya silikatnykh i tugoplavkih nemetallicheskikh materialov (Chemistry and Technology of Silicate and Refractory Nometallic Materials), Leningrad: Nauka, 1989, p. 125.
Napper, D., Polymer Stabilization of Colloidal Dispersions, London: Academic, 1983.
Author information
Authors and Affiliations
Additional information
Original Russian Text © V.P. Finevich, N.A. Allert, T.R. Karpova, V.K. Duplyakin, 2007, published in Russkii Khimicheskii Zhurnal, 2007, Vol. 51, No. 4, pp. 69–74.
Rights and permissions
About this article
Cite this article
Finevich, V.P., Allert, N.A., Karpova, T.R. et al. Composite nanomaterials on the basis of acid-activated montmorillonites. Russ J Gen Chem 77, 2265–2271 (2007). https://doi.org/10.1134/S1070363207120316
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1070363207120316