Abstract
Acid base interactions of octaphenyltetrapyrazinoporphyrazine and its complex with lutetium(III) in acetic and trifluoroacetic acid media were studied, and parameters characterizing equilibria between the acid and base forms were determined. Acid-base interactions of octaphenyltetrapyrazinoporphyrazine involve primarily nitrogen atoms in the pyrazine fragments, while its lutetium(III) complex undergoes protonation at the meso-nitrogen atoms.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Gouterman, M., J. Mol. Spectrosc., 1961, vol. 6, no. 4, p. 138.
Kuz’mitskii, V.A., Solov’ev, K.N., and Tsvirko, M.P., Porfiriny: spektroskopiya, elektrokhimiya, primenenie (Porphyrins: Spectroscopy, Electrochemistry, and Applications), Enikolopyan, N.S., Ed., Moscow: Nauka, 1987, p. 7.
Gaspard, S., Verdaquer, M., and Viovi, R., J. Chem. Res. M., 1979, no. 12, p. 3072.
Bernstein, P.A. and Lever, A.B.P., Inorg. Chim. Acta, 1992, vols. 198–200, no. 3, p. 243.
Stuzhin, P.A., Khelevina, O.G., and Berezin, B.D., Phthalocyanines: Properties and Applications, Leznoff, C.C. and Lever, A.B.P., Eds., New York: VCH, 1996, vol. 4, p. 19.
Stuzhin, P.A., Gabercorn, A.A., Molodkina, O.V., and Pimkov, I.V., Abstracts of Papers, 2nd Int. Conf. on Porphyrins and Phthalocyanines (ICPP-2), Kyoto, June 30–July 5, 2002, pp. 78, 326.
Chirvony, V.S., van Hoek, A., Galievsky, V.A., Sazanovich, I.V., Schaafsma, T.J., and Holten, D., J. Phys. Chem. B, 2000, vol. 104, no. 42, p. 9909.
Rosa, A., Ricciardi, G., Baerends, E.J., Romeo, A., and Scolaro, L.M., J. Phys. Chem. A, 2003, vol. 107, no. 51, p. 11 468.
Golubchikov, O.A., Pukhovskaya, S.G., and Kuvshinova, E.M., Uspekhi khimii porfirinov (Advances in the Porphyrin Chemistry), St. Petersburg: Nauch.-Issled. Inst. Khim. Sankt-Peterb. Gos. Univ., 2004, vol. 4, p. 45.
Berezin, B.D., Klyuev, V.N., and Korzhenevskii, A.B., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1977, vol. 20, no. 4, p. 45.
Berezin, B.D., Klyuev, V.N., and Korzhenevskii, A.B., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1977, vol. 20, no. 3, p. 7.
Stuzhin, P.A., Kabesheva, E.V., and Khelevina, O.G., Koord. Khim., 2003, vol. 29, no. 5, p. 377.
Shkodin, A.M. and Karkuzaki, L.N., Zh. Fiz. Khim., 1959, vol. 33, no. 12, p. 2795.
Fialkov, Yu.Ya. and Borovikov, Yu.Ya., Ukr. Khim. Zh., 1964, vol. 30, no. 2, p. 119.
Shishkin, V.N., Cand. Sci. (Chem.) Dissetation, Ivanovo, 2006.
Lebedeva, T.A., Kulinich, V.P., Kudrik, E.V., Shaposhnikov, G.P., and Kozlova, A.V., Abstracts of Papers, Mezhdunarodnaya konferentsiya po organicheskoi khimii “Organicheskaya khimiya ot Butlerova i Beil’shteina do sovremennosti’ (Int. Conf. on Organic Chemistry “Organic Chemistry from Butlerov and Beilstein to the Present”), St. Petersburg, 2006, p. 524.
Albert, A. and Serjeant, E., Ionization Constants of Acids and Bases, London: Methuen, 1962.
Hammett, L., Physical Organic Chemistry, New York: McGraw-Hill, 1970, 2nd ed.
Hall, N. and Spengeman, W., J. Am. Chem. Soc., 1940, vol. 62, no. 9, p. 2487.
Author information
Authors and Affiliations
Additional information
Original Russian Text © O.G. Khelevina, E.A. Kokareva, A.S. Bubnova, Yu.V. Romanenko, V.P. Kulinich, G.P. Shaposhnikov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 12, pp. 2047–2052.
Rights and permissions
About this article
Cite this article
Khelevina, O.G., Kokareva, E.A., Bubnova, A.S. et al. Acid base interactions of octaphenyltetrapyrazinoporphyrazine and its complex with lutetium(III) in proton-donor media. Russ J Gen Chem 77, 2192–2197 (2007). https://doi.org/10.1134/S1070363207120183
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1070363207120183