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Thermodynamic properties of 1,3-dimethylsilatrane and 1-(2-cyanoethyl)silatrane

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Abstract

The heat capacities of 1,3-dimethylsilatrane and 1-(2-cyanoethyl)silatrane were measured, and their thermodynamic functions were calculated. In the intervals 12–205 and 215–315 K, the heat capacity of 1,3-dimethylsilatrane smoothly varies with temperature. A reproducible thermal effect is observed at ∼315 K, and a G-type transition, in the range 205–215 K. 1-(2-Cyanoethyl)silatrane shows no anomalies in the examined temperature range. Above 260 K, the rate of the growth of the heat capacity with temperature increases.

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References

  1. Termodinamicheskie svoistva individual’nykh veshchestv (Thermodynamic Properties of Pure Substances), Glushko, V.P., Ed., Moscow: Nauka, 1978, vol. 1, book 1.

    Google Scholar 

  2. Voronkov, M.G., Klyuchnikov, V.A., Korchagina, A.N., Danilova, T.F., Shvets, G.N., Baryshok, V.P., and D’yakov, V.M., Izv. Akad. Nauk SSSR, Ser. Khim., 1986, no. 9, p. 1976.

  3. Voronkov, M.G., Baryshok, V.P., Klyuchnikov, V.A., Korchagina, A.N., and Pepekin, V.I., J. Organomet. Chem., 1989, vol. 359, no. 2, p. 169.

    Article  CAS  Google Scholar 

  4. Voronkov, M.G., Sorokin, M.S., Klyuchnikov, V.A., Shvets, G.N., and Pepekin, V.I., J. Organomet. Chem., 1989, vol. 359, no. 3, p. 301.

    Article  CAS  Google Scholar 

  5. Klyuchnikov, V.A., Shvets, G.N., Martynovskaya, L.N., Voronkov, M.G., and Sorokin, M.S., Zh. Fiz. Khim., 1990, vol. 64, no. 1, p. 57.

    CAS  Google Scholar 

  6. Klyuchnikov, V.A., Shvets, G.N., Sorokin, M.S., and Voronkov, M.G., Dokl. Akad. Nauk SSSR, 1985, vol. 282, no. 5, p. 1174.

    CAS  Google Scholar 

  7. Pestunovich, V., Kirpichenko, S., and Voronkov, M., The Chemistry of Organic Silicon Compounds, Rappoport, Z. and Apeloig, Y., Eds., New York: Wiley, 1998, vol. 2, part 2, p. 1447.

    Chapter  Google Scholar 

  8. Fizika i khimiya tverdogo sostoyaniya organicheskikh soedinenii (Physics and Chemistry of the Solid State of Organic Compounds), Pentin, Yu.A., Ed., Moscow: Mir, 1967, p. 75.

    Google Scholar 

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Urkutsk, 664033, Russia

    M. G. Voronkov, G. A. Kuznetsova & V. P. Baryshok

  2. Research Institute of Chemistry, Lobachebsky Nizhni Novgorod State University, Nizhni Novgorod, Russia

    L. Ya. Tsvetkova, E. B. Solovich & N. V. Novoselova

Authors
  1. M. G. Voronkov
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  2. L. Ya. Tsvetkova
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  3. E. B. Solovich
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  4. N. V. Novoselova
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  5. G. A. Kuznetsova
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  6. V. P. Baryshok
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Correspondence to M. G. Voronkov.

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Original Russian Text © M.G. Voronkov, L.Ya. Tsvetkova, E.B. Solovich, N.V. Novoselova, G.A. Kuznetsova, V.P. Baryshok, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 12, pp. 1983–1984.

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Voronkov, M.G., Tsvetkova, L.Y., Solovich, E.B. et al. Thermodynamic properties of 1,3-dimethylsilatrane and 1-(2-cyanoethyl)silatrane. Russ J Gen Chem 77, 2128–2129 (2007). https://doi.org/10.1134/S1070363207120092

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  • DOI: https://doi.org/10.1134/S1070363207120092

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