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Alkylation of alkali metal salts of hydroperoxides with haloalkanes in dipolar nonhydroxyl solvents

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Abstract

The possibility of alkylation with chloroalkanes of cumyl hydroperoxide sodium salt hexahydrate in dopolar nonhydroxyl solvents with high donor numbers was examined. The kinetic featutes of the process in hexamethylphosphoric triamide were studied.

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References

  1. Ivanov, K.I. and Blagova, T.A., Zh. Obshch. Khim., 1952, vol. 22, no. 3, p. 784.

    CAS  Google Scholar 

  2. Sokolov, P.A. and Aleksandrov, Yu.A., Usp. Khim., 1978, vol. 47, no. 2, p. 307.

    CAS  Google Scholar 

  3. Lyavinets, A.S., Zh. Fiz. Khim., 2000, vol. 74, no. 7, p. 1198.

    CAS  Google Scholar 

  4. Lyavinets, A.S., Abramyuk, I.S., and Choban, A.F., Zh. Obshch. Khim., 2004, vol. 74, no. 7, p. 1157.

    Google Scholar 

  5. Gutmann, V., Coordination Chemistry in Non-Aqueous Solutions, Vienna: Springer, 1968. Translated under the title Khimiya koordinatsionnykh soedinenii v nevodnykh rastvorakh, Moscow: Mir, 1971, p. 202.

    Google Scholar 

  6. Choban, A.F. and Lyavinets’, O.S., Ukr. Khim. Zh., 1997, vol. 63, no. 2, p. 117.

    CAS  Google Scholar 

  7. Abramyuk, I.S. and Lyavinets, A.S., Zh. Anal. Khim., 1994, vol. 49, no. 6, p. 599.

    CAS  Google Scholar 

  8. Gordon, A.J. and Ford, R.A., The Chemist’s Companion. A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.

    Google Scholar 

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Authors and Affiliations

  1. Fed’kovich National University, ul. Kotsyubinskogo 2, Chernovtsy, 58012, Ukraine

    A. F. Choban, I. S. Abramyuk & A. S. Lyavinets

Authors
  1. A. F. Choban
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  2. I. S. Abramyuk
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  3. A. S. Lyavinets
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Additional information

Original Russian Text © A.F. Choban, I.S. Abramyuk, A.S. Lyavinets, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 12, pp. 1950–1954.

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Choban, A.F., Abramyuk, I.S. & Lyavinets, A.S. Alkylation of alkali metal salts of hydroperoxides with haloalkanes in dipolar nonhydroxyl solvents. Russ J Gen Chem 77, 2096–2100 (2007). https://doi.org/10.1134/S1070363207120031

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  • DOI: https://doi.org/10.1134/S1070363207120031

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