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Kinetics of the reaction between [chloro(phenyl)arsanyl]acetic and chloroacetic acids

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Abstract

The reaction between [chloro(phenyl)arsanyl]acetic and chloroacetic acids proceeds in alkaline aqueous medium by the Sn2 mechanism and is accompanied by alkaline hydrolysis of chloroacetic acid. Mean rate constants and thermodynamic parameters of the reaction are evaluated.

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References

  1. Rakhmatullin, R.R., Emelyushin, R.E., and Gavrilov, V.I., Zh. Obshch. Khim., 1999, vol. 69, no. 9, p. 1443.

    Google Scholar 

  2. Doak, G.O. and Freedman, L.D., Organometallic Compounds of Arsenic, Antimony, and Bismuth, New York: Wiley, 1970, p. 64.

    Google Scholar 

  3. Dub, M., Organometallic Compounds, Berlin: Springer, 1966, vol III, p. 206.

    Google Scholar 

  4. Emmanuel’, N.M. and Knorre, D.G., Kurs khimicheskoi kinetiki (Handbook on Chemical Kinetics), Moscow: Vysshaya Shkola, 1984.

    Google Scholar 

  5. Braunholtz, J.T. and Mann, F.G., J. Chem. Soc., 1957, no. 7, p. 3285.

  6. Yur’ev, Yu.K., Prakticheskie raboty po organicheskoi khimii (Manual on Organic Chemistry), Moscow: Mosk. Gos. Univ., 1963, vol. III, p. 228.

    Google Scholar 

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Authors and Affiliations

  1. Kazan State Technological University, ul. K. Marksa 68, Kazan, Tatarstan, 420015, Russia

    R. R. Rakhmatullin, O. A. Selyutina & V. I. Gavrilov

Authors
  1. R. R. Rakhmatullin
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  2. O. A. Selyutina
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  3. V. I. Gavrilov
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Correspondence to R. R. Rakhmatullin.

Additional information

Original Russian Text © R.R. Rakhmatullin, O.A. Selyutina, V.I. Gavrilov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 11, pp. 1923–1925.

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Rakhmatullin, R.R., Selyutina, O.A. & Gavrilov, V.I. Kinetics of the reaction between [chloro(phenyl)arsanyl]acetic and chloroacetic acids. Russ J Gen Chem 77, 1972–1974 (2007). https://doi.org/10.1134/S1070363207110229

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  • DOI: https://doi.org/10.1134/S1070363207110229

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