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Synthesis, spectra, and complexing properties of polyoxyethylene-substituted 5,15-diphenylporphyrins

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Abstract

Porphyrins with two opposite meso-phenyl substituents of the macroring linked via o-positions by polyoxyethylene bridges of various lengths were prepared. Their spectra and complexing properties toward Zn2+ and 1,4-diazabicyclo[2.2.2]octane were examined. The rate constants of formation and stability constants of the corresponding complexes were determined, and the concentration ranges of their formation were evaluated.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153000, Russia

    G. M. Mamardashvili, O. M. Kulikova, N. Zh. Mamardashvili & O. I. Koifman

  2. Ivanovo State University of Chemical Technology, Ivanovo, Russia

    N. Zh. Mamardashvili

Authors
  1. G. M. Mamardashvili
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  2. O. M. Kulikova
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  3. N. Zh. Mamardashvili
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  4. O. I. Koifman
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Correspondence to G. M. Mamardashvili.

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Original Russian Text © G.M. Mamardashvili, O.M. Kulikova, N.Zh. Mamardashvili, O.I. Koifman, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 11, pp. 1915–1922.

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Mamardashvili, G.M., Kulikova, O.M., Mamardashvili, N.Z. et al. Synthesis, spectra, and complexing properties of polyoxyethylene-substituted 5,15-diphenylporphyrins. Russ J Gen Chem 77, 1965–1971 (2007). https://doi.org/10.1134/S1070363207110217

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  • DOI: https://doi.org/10.1134/S1070363207110217

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