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Synthesis and magnetic properties of the complex of 3-acetylquinoxalin-2(1H)-one with Cu(II)

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Abstract

The complex CuHL(NO3)2 · H2O, where HL = 3-acetylquinoxalin-2(1H)-one was synthesized and studied. Elemental analysis, magnetochemistry, and ESR, electronic, and IR spectroscopy were used to show that this complex is a polymer with the copper ion having a distorted octahedral surrounding. Each ligand bidentately coordinates to one copper ion and monodentately coordinates to the second.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    T. B. Makeeva, A. R. Mustafina & V. A. Mamedov

  2. Zavoiskii Physicotechnical Institute, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    T. A. Ivanova & I. V. Ovchinnikov

  3. Kazan State Energetic University, Kazan, Tatarstan, Russia

    A. N. Turanov

Authors
  1. T. B. Makeeva
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  2. T. A. Ivanova
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  3. I. V. Ovchinnikov
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  4. A. R. Mustafina
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  5. V. A. Mamedov
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  6. A. N. Turanov
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Correspondence to T. B. Makeeva.

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Original Russian Text © T.B. Makeeva, T.A. Ivanova, I.V. Ovchinnikov, A.R. Mustafina, V.A. Mamedov, A.N. Turanov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 11, pp. 1876–1880.

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Makeeva, T.B., Ivanova, T.A., Ovchinnikov, I.V. et al. Synthesis and magnetic properties of the complex of 3-acetylquinoxalin-2(1H)-one with Cu(II). Russ J Gen Chem 77, 1928–1932 (2007). https://doi.org/10.1134/S107036320711014X

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  • DOI: https://doi.org/10.1134/S107036320711014X

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