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Synthesis and properties of fluorinated 2-benzoylcyclohexane-1,3-diones

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Abstract

Fluorinated 2-benzoylcyclohexane-1,3-diones were obtained by the O-C isomerization of the corresponding 3-benzoyloxycyclohex-2-en-1-ones under the action of acetone cyanohydrin in the presence of triethylamine in the medium of absolute acetonitrile. The structure of the target compounds was investigated by the means of IR and NMR spectroscopy, and X-ray diffraction analysis.

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Authors and Affiliations

  1. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, ul. Akad. Kuprievicha 5/2, Minsk, 22014, Belarus

    T. S. Khlebnikova, V. G. Isakova, A. V. Baranovskii & F. A. Lakhvich

  2. Research Institute of Physicochemical Problems, Belarus State University, Minsk, Belarus

    A. S. Lyakhov

Authors
  1. T. S. Khlebnikova
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  2. V. G. Isakova
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  3. A. V. Baranovskii
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  4. F. A. Lakhvich
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  5. A. S. Lyakhov
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Correspondence to T. S. Khlebnikova.

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Original Russian Text © T.S. Khlebnikova, V.G. Isakova, A.V. Baranovskii, F.A. Lakhvich, A.S. Lyakhov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 10, pp. 1657–1664.

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Khlebnikova, T.S., Isakova, V.G., Baranovskii, A.V. et al. Synthesis and properties of fluorinated 2-benzoylcyclohexane-1,3-diones. Russ J Gen Chem 77, 1724–1731 (2007). https://doi.org/10.1134/S1070363207100118

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  • DOI: https://doi.org/10.1134/S1070363207100118

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