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Effect of the structure of cyclic N-nitramines on the rate and mechanism of their thermolysis

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Abstract

Manometry together IR spectroscopy, mass spectrometry, and chromatography were used to study thermolysis of six-membered cyclic N-nitramines containing one, two, or three nitramine fragments, as well as oxo, gem-dinitro, azide, nitroimino, amino, and tetrazolyl functions. An effect of the conformation and functional groups on the rate, mechanism, and activation parameters of the limiting stage of themolysis was revealed.

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Authors and Affiliations

  1. Siberian State Technological University, pr. Mira 82, Krasnoyarsk, 660049, Russia

    R. S. Stepanov, L. A. Kruglyakova & A. M. Astakhov

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  1. R. S. Stepanov
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  2. L. A. Kruglyakova
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  3. A. M. Astakhov
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Original Russian Text © R.S. Stepanov, L.A. Kruglyakova, A.M. Astakhov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 7, pp. 1211–1217.

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Stepanov, R.S., Kruglyakova, L.A. & Astakhov, A.M. Effect of the structure of cyclic N-nitramines on the rate and mechanism of their thermolysis. Russ J Gen Chem 77, 1293–1299 (2007). https://doi.org/10.1134/S1070363207070237

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  • DOI: https://doi.org/10.1134/S1070363207070237

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