Abstract
The thermodynamic characteristics of aqueous solutions of mono-, di-, tri-, and tetraethylene glycols were calculated in the entire range of compositions of the mixtures for various temperatures. The specific and nonspecific terms of the total energy of intermolecular interaction were determined within the framework of a model approach using the internal pressure as a measure of nonspecific interactions in a liquid. The concentration ranges with different types of intercomponent association and of structural organization of solutions depend on the temperature and number of ether groups in the glycol molecules.
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Kartsev, V.N., Rodnikova, M.N., Shtykov, S.N., and Bartel, J., Zh. Fiz. Khim., 2003, vol. 77, no. 8, p. 1456.
Kartsev, V.N., Rodnikova, M.N., Bartel, J., and Shtykov, S.N., Zh. Fiz. Khim., 2002, vol. 76, no. 6, p. 1016.
Ivanov, E.V. and Abrosimov, V.K., Zh. Strukt. Khim., 2005, vol. 46, no. 5, p. 889.
Sakurai, M., J. Chem. Eng. Data, 1991, vol. 36, no. 4, p. 424.
George, J. and Sastry, N.V., Fluid Phase Equil., 2004, vol. 216, no. 1, p. 307.
Muller, E.A. and Rasmussen, P., J. Chem. Eng. Data, 1991, vol. 36, no. 2, p. 214.
Huot, J.Y., Battistel, E., Lumry, R., Villeneuve, G., Lavallee, J.F., Anusem, A., and Jolicoeur, C., J. Solution Chem., 1988, vol. 17, no. 7, p. 601.
Pal, A. and Singh, W., J. Chem. Eng. Data, 1997, vol. 42, no. 2, p. 234.
Douheret, G., Davis, M.I., Fjellanger, I.J., and Hoiland, H., J. Chem. Soc., Faraday Trans. 1, 1997, vol. 93, no. 10, p. 1943.
Nan, Z., Liu, B., and Tan, Z., J. Chem. Thermodyn., 2002, vol. 34, no. 6, p. 915.
Dyment, O.N., Kazanskii, K.S., and Miroshnikov, A.M., Glikoli i drugie proizvodnye okisei etilena i propilena (Glycols and Other Derivatives of Ethylene and Propylene Oxides), Moscow: Khimiya, 1976.
Uosaki, Y., Kitaura, S., and Moriyoshi, T., J. Chem. Eng. Data, 2006, vol. 51, no. 2, p. 423.
Mikhailov, V.A. and Kirgintsev, A.N., Zh. Fiz. Khim., 1962, vol. 36, no. 9, p. 2085.
Dack, M.R., Aust. J. Chem., 1975, vol. 28, no. 8, p. 1643.
Holtzer, A. and Emerson, M.F., J. Phys. Chem., 1969, vol. 73, no. 1, p. 26.
Vargaftik, N.B., Spravochnik po teplofizicheskim svoistvam gazov i zhidkostei (Handbook of Thermal Properties of Gases and Liquids), Moscow: Nauka, 1972.
Knauth, P. and Sabbah, R., Bull. Soc. Chim. Fr., 1988, vol. 53, no. 6, p. 834.
Steel, W.V., Chirico, R.D., Knipmeyer, S.E., and Nguen, A., J. Chem. Eng. Data, 2002, vol. 47, no. 4, p. 689.
Zaichikov, A.M., Zh. Obshch. Khim., 2005, vol. 75, no. 8, p. 1320.
Matsumoto, Y., Touhara, H., Nakanishi, K., and Watanabe, N., J. Chem. Thermodyn., 1977, vol. 9, no. 8, p. 801.
Hamam, S.E.M., Benson, G.C., and Kumaran, M.K., J. Chem. Thermodyn., 1985, vol. 17, no. 10, p. 973.
Atovmyan, E.G., Baturin, S.M., and Fedotova, T.N., Vysokomol. Soedin., Ser. A, 1989, vol. 31, no. 8, p. 1685.
Rudan-Tasic, D. and Klofutar, C., J. Mol. Liq., 2004, vol. 111, no. 1, p. 125.
Krasnoperova, A.P., Surov, Yu.N., and Pivnenko, N.S., Zh. Obshch. Khim., 1995, vol. 65, no. 12, p. 2053.
Ginzburg, I.M., Strelkova, L.F., and Ragozina, T.N., Zh. Obshch. Khim., 1988, vol. 58, no. 5, p. 1116.
Schrodle, S., Buchner, R., and Kunz, W., J. Phys. Chem. (B), 2004, vol. 108, no. 20, p. 6281.
Zaichikov, A.M., Zh. Obshch. Khim., 2006, vol. 76, no. 4, p. 660.
Koga, Y., J. Phys. Chem., 1996, vol. 100, no. 13, p. 5172.
Kirkwood, J.G. and Buff, F.P., J. Chem. Phys., 1951, vol. 19, no. 6, p. 774.
Matteoli, E., J. Phys. Chem. B, 1997, vol. 101, no. 47, p. 9800.
Marcus, Y., Monatsh. Chem., 2001, vol. 132, no. 12, p. 1387.
Dethlefsen, C. and Hvidt, A., J. Chem. Thermodyn., 1985, vol. 17, no. 2, p. 193.
Villamanan, M.A., Gonzalez, C., and Van Ness, H.C., J. Chem. Eng. Data, 1984, vol. 29, no. 4, p. 427.
Herskowitz, M. and Gottlieb, M., J. Chem. Eng. Data, 1984, vol. 29, no. 2, p. 173.
Herskowitz, M. and Gottlieb, M., J. Chem. Eng. Data, 1984, vol. 29, no. 4, p. 450.
Marcus, Y., J. Mol. Liq., 2003, vol. 107, nos. 1–3, p. 109.
Gubskaya, A.V. and Kusalik, P.G., J. Phys. Chem. A, 2004, vol. 35, no. 108, p. 7165.
Belousov, V.P. and Panov, M.Y., Thermodynamic Properties of Aqueous Solutions of Organic Substances, Boca Raton: CRC, 1994.
Grineva, O.V., Zh. Strukt. Khim., 2006, vol. 47, no. 1, p. 185.
Douheret, G., Pal, A., Hoiland, H., and Davis, M.I., J. Chem. Thermodyn., 1991, vol. 23, no. 5, p. 569.
Zaichikov, A.M., Nogovitsyn, E.A., Zheleznyak, N.I., and Krestov, G.A., Zh. Fiz. Khim., 1988, vol. 62, no. 11, p. 3118.
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Original Russian Text © A.M. Zaichikov, M.A. Krest’yaninov, 2007, published in Zhurnal Obshchei Khimii, 2007, vol. 77, No. 7, pp. 1134–1143.
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Zaichikov, A.M., Krest’yaninov, M.A. Thermodynamic characteristics and intermolecular interactions in aqueous solutions of oxyethylated glycols. Russ J Gen Chem 77, 1218–1226 (2007). https://doi.org/10.1134/S1070363207070134
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DOI: https://doi.org/10.1134/S1070363207070134