Skip to main content
SpringerLink
Log in

Chiral derivatives of titanium with terpene alcohols

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

A series of substituted alkoxy compounds of titanium were prepared by reactions of titanium isopropylate with 1-menthol, 1-borneol, (±)-isoborneol, and (-)-trans-3-hydroxymyrtanol. The specific rotation of the alcoholates was shown to be an additive function of the number of the terpene ligands. For titanium bornylates, the optical activity is a linear function of the degree of substitution. For trans-3-hydroxymyrtanol derivatives, an inversion of the optical rotation angle is observed along with an additive dependence of the optical activity on the degree of substitution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Potvin, P.G., Gau, R., Kwong, P.C., and Bianchen, S.S., Can. J. Chem., 1989, vol. 67, no. 8, p. 1523.

    Article  CAS  Google Scholar 

  2. Potvin, P.G. and Fieldhouse, B.G., Tetrahedron Asymm., 1999, vol. 10, no. 9, p. 1661.

    Article  CAS  Google Scholar 

  3. Davis, Th.J., Carrol, P.J., and Walsh, P.J., J. Organomet. Chem., 2002, vol. 663, p. 70.

    Article  CAS  Google Scholar 

  4. Buonora, P., Olsen, J.-C., and Oh, T., Tetrahedron, 2001, vol. 57, no. 29, p. 6099.

    Article  CAS  Google Scholar 

  5. Banks, M.R., Blake, Al.J., Cadogan, J.I.G., Doyle, Al.A., Gosney, I., Hodgson, Ph.K., and Thorburn, P., Tetrahedron, 1996, vol. 52, no. 11, p. 4079.

    Article  CAS  Google Scholar 

  6. Santora, Br.P., Larsen, An.O., and Gange, M.R., Organometallics, 1998, vol. 17, no. 15, p. 3138.

    Article  CAS  Google Scholar 

  7. Groaning, M.D., Rowe, Br.J., and Spilling, Chr.D., Tetrahedron Lett., 1998, vol. 39, no. 31, p. 5485.

    Article  CAS  Google Scholar 

  8. Hanawa, H., Hashimoto, T., and Maruoka, K., J. Am. Chem. Soc., 2003, vol. 125, no. 7, p. 1708.

    Article  CAS  Google Scholar 

  9. Potvin, P.G. and Bianchen, S.S., J. Org. Chem., 1992, vol. 57, no. 24, p. 6629.

    Article  CAS  Google Scholar 

  10. Perez, Yo., de Hierro, Is., Fajardo, M., and Otero, An., J. Organomet. Chem., 2003, vol. 679, p. 220.

    Article  CAS  Google Scholar 

  11. Klabunovskii, E.I., Karpeiskaya, E.I., Dzhardimalieva, G.I., Golubova, N.D., and Pomogailo, A.D., Izv. Ross. Akad. Nauk, Ser. Khim., 1999, no. 9, p. 1739.

  12. Boyle, Th.J., Barnes, D.L., Heppert, J.A., Morales, L., and Takusagawa, F., Organometallics, 1992, vol. 11, no. 3, p. 1112.

    Article  CAS  Google Scholar 

  13. Davis, Th.J., Balsell, J., Carrol, P.J., and Walsh, P.J., Org. Lett., 2001, vol. 3, no. 14, p. 2161.

    Article  CAS  Google Scholar 

  14. Kayan, As., J. Inorg. Organomet. Polym., 2003, vol. 13, no. 1, p. 29.

    Article  CAS  Google Scholar 

  15. Matveev, Yu.S., Kuchin, A.V., Kataeva, N.A., and Kozhemyakina, T.I., Koord. Khim., 1999, vol. 25, no. 12, p. 900.

    Google Scholar 

  16. Matveev, Yu.S., Kataeva, N.A., and Kuchin, A.V., Khim. Rastit. Syr’ya, 1999, no. 1, p. 13.

  17. Frolova, L.L., Cand. Sci. (Chem.) Dissertation, Ufa, 2005.

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Komi Research Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, Komi Republic, 167982, Russia

    Yu. S. Matveev, L. L. Frolova, N. A. Kataeva & A. V. Kuchin

Authors
  1. Yu. S. Matveev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. L. Frolova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. A. Kataeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Kuchin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. S. Matveev.

Additional information

Original Russian Text © Yu.S. Matveev, L.L. Frolova, N.A. Kataeva, A.V. Kuchin, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 7, pp. 1112–1119.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Matveev, Y.S., Frolova, L.L., Kataeva, N.A. et al. Chiral derivatives of titanium with terpene alcohols. Russ J Gen Chem 77, 1196–1203 (2007). https://doi.org/10.1134/S1070363207070109

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363207070109

Keywords

Search

Navigation