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Acceptor power of cations in donor-acceptor interactions

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Abstract

Published data concerning quantitative evaluation of the reactivity of cations in donor-acceptor interactions were analyzed. The “relative acceptor numbers” of C°2+, Mn2+, Ni2+, Al3+, and Ga3+ were determined polarographically: 2.16±0.32, 2.25±0.23, ∼1.70, 2.35±0.27, and 2.42±0.21, respectively. The known “relative acceptor numbers” for 21 cations were systematized, and a linear correlation between the ionization potentials and “relative acceptor numbers” of “hard” cations was revealed.

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Authors and Affiliations

  1. All-Russia Research Institute of Chemical Technology, Kashirskoe shosse 33, Moscow, 115409, Russia

    E. P. Buchikhin & A. Yu. Kuznetsov

  2. Mendeleev Russian University of Chemical Engineering, Moscow, Russia

    A. M. Chekmarev & N. A. Bobyrenko

Authors
  1. E. P. Buchikhin
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  2. A. M. Chekmarev
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  3. A. Yu. Kuznetsov
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  4. N. A. Bobyrenko
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Correspondence to E. P. Buchikhin.

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Original Russian Text © E.P. Buchikhin, A.M. Chekmarev, A.Yu. Kuznetsov, N.A. Bobyrenko, 2007, published in Zhurnal Obshchei Khimii, 2007, vol. 77, No. 7, pp. 1057–1063.

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Buchikhin, E.P., Chekmarev, A.M., Kuznetsov, A.Y. et al. Acceptor power of cations in donor-acceptor interactions. Russ J Gen Chem 77, 1141–1147 (2007). https://doi.org/10.1134/S1070363207070018

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