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Synthesis and some properties of tetrakis-3,5-di-tert-butyl-4-hydroxybenzylated calix[4]resorcinols

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Abstract

A method for the synthesis of new calix[4]resorcinols tetra-3,5-di-tert-butyl-4-hydroxybenzyl derivatives is developed. Their interaction with methyldichlorophosphonate, dimethyldichlorosilane in the presence of a base leads to formation of organophosphorus-organosilicon cavitands. Acetylation of hydroxybenzylated calix[4]resorcinols with acetic anhydride leads to products of either incomplete or full acetylation depending on experimental conditions.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Acad. Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    E. M. Kasymova, A. R. Burilov, M. A. Pudovik, A. V. Chernova, R. R. Shagidullin & A. I. Konovalov

  2. Kazan State Technological University, Kazan, Tatarstan, Russia

    N. A. Mukmeneva, S. V. Bukharov & G. N. Nugumanova

Authors
  1. E. M. Kasymova
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  2. A. R. Burilov
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  3. N. A. Mukmeneva
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  4. S. V. Bukharov
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  5. G. N. Nugumanova
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  6. M. A. Pudovik
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  7. A. V. Chernova
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  8. R. R. Shagidullin
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  9. A. I. Konovalov
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Additional information

Original Russian Text © E.M. Kasymova, A.R.Burilov, N.A. Mukmeneva, S.V. Bukharov, G.N. Nugumanova, M.A. Pudovik, A.V. Chernova, R.R. Shagidullin, A.I. Konovalov, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 3, pp. 494–504.

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Kasymova, E.M., Burilov, A.R., Mukmeneva, N.A. et al. Synthesis and some properties of tetrakis-3,5-di-tert-butyl-4-hydroxybenzylated calix[4]resorcinols. Russ J Gen Chem 77, 458–468 (2007). https://doi.org/10.1134/S1070363207030206

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  • DOI: https://doi.org/10.1134/S1070363207030206

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