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Synthesis and structure of phosphorylated nitrocyclohexenes

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Abstract

Diene condensations of 2-nitro-and 2-bromo-2-nitroethenylphosphonates with 2,3-dimethyl-1,3-butadiene, as well as with 2,4-dihydro-and 3-methyl-2,4-dihydrothiophene 1,1-dioxides that generate 1,3-butadiene and isoprene under the reaction conditions were effected. (6-Nitrocyclohex-3-en-1-yl)phosphonates and their dehydrogenation and/or dehydrohalogenation products, namely nitrocyclohexadienyl-and nitrophenylphosphonates were prepared. The structure of the obtained compounds was proved by IR and 1H and 31P NMR spectroscopy, and independent synthesis.

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Authors and Affiliations

  1. Hertsen Russian State Pedagogical University, nab. r. Moiki 48, St. Petersburg, 191186, Russia

    V. M. Berestovitskaya, N. A. Anisimova, A. A. Kuzhaeva, G. A. Berkova & L. I. Deiko

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  1. V. M. Berestovitskaya
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  2. N. A. Anisimova
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  3. A. A. Kuzhaeva
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  4. G. A. Berkova
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  5. L. I. Deiko
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Original Russian Text © V.M. Berestovitskaya, N.A. Anisimova, A.A. Kuzhaeva, G.A. Berkova, L.I. Deiko, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 1, pp. 29–40.

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Berestovitskaya, V.M., Anisimova, N.A., Kuzhaeva, A.A. et al. Synthesis and structure of phosphorylated nitrocyclohexenes. Russ J Gen Chem 77, 25–35 (2007). https://doi.org/10.1134/S1070363207010045

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  • DOI: https://doi.org/10.1134/S1070363207010045

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