Skip to main content
SpringerLink
Log in

NH-acid properties of porphyrins in acetonitrile

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The thermodynamics of acid dissociation of synthetic porphyrins (H2P) in alkaline acetonitrile solution is studied. The low stability of the anionic species is attributed to the previously formulated electronic, steric, and solvation factors. The solvent plays an important role in the stabilization of anionic porphyrin species in acetonitrile. The electronic absorption spectra of anionic species of H2P are analyzed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Andrianov, V.G., Malkova, O.V., and Berezin, D.B., Uspekhi khimii porfirinov (Advances in Porphyrin Chemistry), Golubchikov, O.A., Ed., St. Petersburg: Nauchno-Issled. Inst. Khimii S.-Peterb. Gos. Univ., 2001, vol. 3, p. 107.

    Google Scholar 

  2. Hambright, P., Porphyrins and Metalloporphyrins, Smith, K.M., Ed., Elsevier: Oxford, 1975, p. 233.

    Google Scholar 

  3. Berezin, B.D., Coordination Compounds of Porphyrins and Phtalocyanine, New York: Wiley, 1981.

    Google Scholar 

  4. Senge, M.O., Forsyth, T.P., Nguyen, L.T., and Smith, K.M., Angew. Chem., Int. Ed. Engl., 1994, vol. 33, no. 23/24, p. 2485.

    Google Scholar 

  5. Medforth, C.J., The Porphyrin Handbook, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., San Diego: Academic, 2000, vol. 5, p. 1.

    Google Scholar 

  6. Gurinovich, G.P., Sevchenko, A.N., and Solov’ev, K.N., Spektroskopiya khlorofilla i rodstvennykh soedinenii (Spectroscopy of Chlorophyll and Related Compounds), Minsk: Nauka i Tekhnika, 1968.

    Google Scholar 

  7. Chirvony, V.S., Hoek, A. van, Galievskii, V.A., Sazanovich, I.V., Schaafsma, T.J., and Holten, D., J. Phys. Chem. B, 2000, vol. 104, no. 42, p. 9909.

    Article  CAS  Google Scholar 

  8. Sheinin, V.B., Andrianov, V.G., Berezin, B.D., and Koroleva, T.A., Zh. Org. Khim., 1985, vol. 21, no. 7, p. 1564.

    CAS  Google Scholar 

  9. Tsvetkova, I.V., Andrianov, V.G., and Berezin, B.D., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1994, vol. 37, no. 1, p. 73.

    CAS  Google Scholar 

  10. Berezin, B.D. and Berezin, D.B., Uspekhi khimii porfirinov (Advances in Porphyrin Chemistry), Golubchikov, O.A., Ed., St. Petersburg: Nauchno-Issled. Inst. Khimii S.-Peterb. Gos. Univ., 1999, vol. 2, p. 128.

    Google Scholar 

  11. Senge, M.O., The Porphyrin Handbook, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., San Diego: Academic, 2000, vol. 1, p. 239.

    Google Scholar 

  12. Berezin, D.B., Andrianov, V.G., and Semeikin, A.S., Opt. Spektrosk., 1996, vol. 80, no. 4, p. 618.

    CAS  Google Scholar 

  13. Lomova, T.N. and Berezin, D.B., Problemy khimii rastvorov. Biologicheski aktivnye veshchestva v rastvorakh (Problems of Solution Chemistry. Biologically Active Substances in Solutions), Kutepov, A.M., Ed., Moscow: Nauka, 2001, p. 326.

    Google Scholar 

  14. Petrov, O.A., Koord. Khim., 2001, vol. 27, no. 7, p. 483.

    Google Scholar 

  15. Berezin, D.B., Toldina, O.V., and Kumeev, R.S., Zh. Fiz. Khim., 2004, vol. 78, no. 8, p. 1427.

    CAS  Google Scholar 

  16. Fialkov, V.Ya., Rastvoritel’ kak sredstvo upravleniya khimicheskim protsessom (Solvent as a Means for Controlling a Chemical Process), Leningrad: Khimiya, 1990.

    Google Scholar 

  17. Krestov, G.A., Novoselov, N.P., and Perelygin, I.S., Problemy khimii rastvorov. Ionnaya sol’vatatsiya (Problems of Solution Chemistry. Ion Solvation), Krestov, G.A., Ed., Moscow: Nauka, 1987.

    Google Scholar 

  18. Kolthoff, I.N., Chantooni, M.K., and Bhowmik, S., Anal. Chem., 1967, vol. 39, no. 13, p. 1627.

    Article  CAS  Google Scholar 

  19. Takeda, J. and Sato, M., Chem. Lett., 1995, no. 11, p. 971.

  20. Chirvony, V.S., Sazanovich, I.V., Galievsky, V.A., Hoek, A. van, Schaafsma, T.J., Malinovskii, V.L., and Holten, D., J. Phys. Chem. B, 2001, vol. 105, no. 32, p. 7818.

    Article  Google Scholar 

  21. Ichimura, K., Sakuragi, M., Morii, H., Yasuike, M., Fukui, M., and Ohno, O., Inorg. Chim. Acta, 1991, vol. 182, p. 83.

    Article  CAS  Google Scholar 

  22. Gordon, A.J. and Ford, R.A., The Chemist’s Companion, New York: Wiley, 1972.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, pr. F. Engel’sa 7, Ivanovo, 153000, Russia

    D. B. Berezin, O. V. Malkova & V. G. Andrianov

  2. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    D. B. Berezin & N. I. Islamova

Authors
  1. D. B. Berezin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. I. Islamova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. V. Malkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Andrianov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © D.B. Berezin, N.I. Islamova, O.V. Malkova, V.G. Andrianov, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 6, pp. 1042–1047.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Berezin, D.B., Islamova, N.I., Malkova, O.V. et al. NH-acid properties of porphyrins in acetonitrile. Russ J Gen Chem 76, 997–1002 (2006). https://doi.org/10.1134/S1070363206060260

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363206060260

Keywords

Search

Navigation