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Reactions of alkoxy and amino derivatives of silacyclobutane with amino alcohols

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Abstract

2-(N,N-Dimethylamino)ethanol readily replaces the MeO and Et2N groups in 1-methoxy-1-methyl-, 1,1-dimethoxy-, 1-diethylamino-1-methyl-and 1,1-bis(diethylamino)-1-silacyclobutanes to form dimethylaminoethoxy derivatives. Triethanolamine and N,N-bis(2-hydroxyethyl)glycinamide split the silacyclobutane ring in 1,1-dimethoxy-1-silacyclobutane to form 1-propylsilathrane and 1-propyl-2-azasilathran-3-one, respectively.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    V. A. Pestunovich, N. F. Lazareva & A. I. Albanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    E. N. Buravtseva & L. E. Gusel’nikov

Authors
  1. V. A. Pestunovich
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  2. N. F. Lazareva
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  3. A. I. Albanov
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  4. E. N. Buravtseva
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  5. L. E. Gusel’nikov
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Additional information

Original Russian Text © V.A. Pestunovich, N.F. Lazareva, A.I. Albanov, E.N. Buravtseva, L.E. Gusel’nikov, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 6, pp. 973–977.

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Pestunovich, V.A., Lazareva, N.F., Albanov, A.I. et al. Reactions of alkoxy and amino derivatives of silacyclobutane with amino alcohols. Russ J Gen Chem 76, 931–935 (2006). https://doi.org/10.1134/S1070363206060132

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  • DOI: https://doi.org/10.1134/S1070363206060132

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