Abstract
The catalytic properties of complexes of network polytetrapyrazinoporphyrazine with Cu2+, Co2+, and Fe2+ in the decomposition of hydrogen peroxide under heterogeneous conditions were studied. These compounds exhibit catalytic activity which depends on the nature of a metal ion. A comparison of the catalytic properties of the monomeric and polymeric isometallic complexes of tetrapyrazinoporphyrazine reveals an activating effect of the giant conjugated system of the polymeric macroligand.
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Korzhenevskii, A.B., Markova, L.V., Efimova, S.V., Koifman, O.I., and Zelenov, A.A., Zh. Obshch. Khim., 2005, vol. 75, no. 6, p. 1041.
Cook, A.H., J. Chem. Soc., 1938, vol. 60, p. 1761.
Sittig, M., Oxo Processes and Products, Park Ridge, New Jersey: Noyes Development, 1966.
Mazgarov, A.M. and Vil’dakov, A.F., Abstracts of Papers, XVIII Mendeleevskii s”ezd po obshchei i prikladnoi khimii (XVIII Mendeleev Congr. on General and Applied Chemistry), Kazan, 2003, vol. 4, p. 331.
Yu Cai Cao and Xuan Zhen Jiang, J. Mol. Catal. A: Chem., 2002, vol. 184, nos. 1–2, p. 183.
Borisenkova, S.A., Il’ina, L.M., Leonova, E.V., and Rudenko, A.P., Zh. Org. Khim., 1973, vol. 9, no. 9, p. 1827.
Borisenkova, S.A., Erokhin, A.S., Novikov, V.A., and Rudenko, A.P., Zh. Org. Khim., 1975, vol. 11, no. 9, p. 1977.
Maizlish, V.E., Korzhenevskii, A.B., and Klyuev, V.N., Khim. Geterotsikl. Soedin., 1984, no. 9, p. 1257.
Korzhenevskii, A.B., Shikova, T.G., Bykova, V.V., and Koifman, O.I., Zh. Obshch. Khim., 2002, vol. 72, no. 7, p. 1202.
Roginskii, S.E., Berlin, A.A., Golovina, O.A., Dokukina, E.S., Sakharov, M.M., and Cherkashina, L.G., Kinet. Katal., 1963, vol. 4, no. 3, p. 431.
Berezin, B.D. and Shlyapova, A.N., Izv. Vyssh. Uchebn. Zaved., Ser. Khim. Khim. Tekhnol., 1969, vol. 12, no. 12, p. 1641.
Shlyapova, A.N. and Berezin, B.D., Izv. Vyssh. Uchebn. Zaved., Ser. Khim. Khim. Tekhnol., 1971, vol. 14, no. 12, p. 1810.
Shlyapova, A.N. and Berezin, B.D., Tr. Ivanov. Khim.-Tekhnol. Inst., 1973, no. 15, p. 89.
Korzhenevskii, A.B., Markova, L.V., Efimova, S.V., Koifman, O.I., and Krylova, E.V., Zh. Obshch. Khim., 2005, vol. 75, no. 6, p. 1036.
Pobedinskii, S.N., Trofimenko, A.A., and Zharnikova, M.A., Izv. Vyssh. Uchebn. Zaved., Ser. Khim. Khim. Tekhnol., 1985, vol. 28, no. 12, p. 46.
Kreja, L., Monatsh. Chem., 1987, vol. 118, nos. 6–7, p. 717.
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Original Russian Text © A.B. Korzhenevskii, S.V. Efimova, A.A. Zelenov, O.I. Koifman, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 5, pp. 858–861.
For communication II, see [1].
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Korzhenevskii, A.B., Efimova, S.V., Zelenov, A.A. et al. Metal complexes of polymeric tetrapyrazinoporphyrazine of the network structure: III. Catalytic properties. Russ J Gen Chem 76, 822–825 (2006). https://doi.org/10.1134/S1070363206050264
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DOI: https://doi.org/10.1134/S1070363206050264