Abstract
Solvation and complexation of Cu(II), Ni(II), and Co(II) with adipic acid dihydrazide (L) in aqueous and aqueous-ethanol solutions (ethanol mole fraction 0.07–0.68) were studied by spectrophotometry. The formation constants of the species M(LH)3+, ML2+, M2L4+ (μ = Cu2+, Ni2+, Co2+), and also M2L 4+2 and ML 2+2 (μ = Cu2+, Ni2+) were determined. With Cu(II), the complexes Cu(LH) 4+2 , CuL(LH)3+, and Cu2L(LH)5+ were also detected and characterized. Evidence is given for the hydrazide coordination mode: tridentate in ML2+, bidentate in M(LH)3+ and ML 2+2 , and tetradentate in M2L4+ and M2L 4+2 . The ligand exchange reactions involving CuL2+, Cu(LH)3+, Cu(LH) 4+2 , CuL(LH)3+, CuL 2+2 , and Cu2L(LH)5+ in aqueous solutions of Cu(II) were revealed and kinetically characterized by nuclear magnetic relaxation. The heretofore unknown rate constants of formation of these complexes were calculated from the thermodynamic and kinetic parameters. Factors controlling the rate constants of the complex formation and chemical exchange are discussed.
Similar content being viewed by others
References
Bychkova, T.I., Shtyrlin, V.G., Sadykova, E.R., and Zakharov, A.V., Zh. Neorg. Khim., 2000, vol. 45, no. 3, p. 401.
Shakirova, A.R., Bychkova, T.I., Afanas’eva, G.V., Shtyrlin, V.G., and Zakharov, A.V., Abstracts of Papers, XXI Mezhdunarodnaya Chugaevskaya konferentsiya po koordinatsionnoi khimii (XXI Int. Chugaev Conf. on Coordination Chemistry), Kiev, 2003, p. 415.
Bychkova, T.I., Shtyrlin, V.G., Sadykova, E.R., Zakharov, A.V., and Popova, Yu.I., Zh. Obshch. Khim., 2001, vol. 71, no. 4, p. 986.
Bychkova, T.I., Kasimova, L.F., Shtyrlin, V.G., and Zakharov, A.V., in Sbornik nauchnykh trudov, posvyashchennyi yubileyu prof. V.F. Toropovoi (Coll. of Scientific Papers, Dedicated to the Jubilee of Prof. V.F. Toropova), Kazan: Kazan. Gos. Univ., 2000, p. 64.
Bychkova, T.I., Boos, G.A., and Aksenova, L.F., Zh. Fiz. Khim., 1991, vol. 65, no. 9, p. 2413.
Sal’nikov, Yu.I., Glebov, A.N., and Devyatov, F.V., Poliyadernye kompleksy v rastvorakh (Polynuclear Complexes in Solutions), Kazan: Kazan. Gos. Univ., 1989.
Beck, M.T. and Nagypal, I., Chemistry of Complex Equilibria, Budapest: Akad. Kiado, 1985.
Bychkova, T.I., Shtyrlin, V.G., and Zakharov, A.V., Zh. Neorg. Khim., 1989, vol. 34, no. 11, p. 2820.
Shtyrlin, V.G., Gogolashvili, E.L., and Zakharov, A.V., J. Chem. Soc., Dalton Trans., 1989, no. 7, p. 1293.
Ushanov, V.V., Shtyrlin, V.G., Nazmutdinova, G.A., and Zakharov, A.V., Zh. Neorg. Khim., 1997, vol. 42, no. 12, p. 2019.
Swift, T.J. and Connick, R.E., J. Chem. Phys., 1962, vol. 37, no. 2, p. 307.
Shtyrlin, V.G., Zakharov, A.V., Kireeva, N.N., and Saprykova, Z.A., Koord. Khim., 1987, vol. 13, no. 7, p. 875.
Afanas’eva, G.V., Bychkova, T.I., Shtyrlin, V.G., Shakirova, A.R., Garipov, R.R., Zyavkina, Yu.I., and Zakharov, A.V., Russ. J. Gen. Chem., 2006, vol. 76, no. 3, p. 346.
Zakharov, A.V. and Shtyrlin, V.G., Bystrye reaktsii obmena ligandov (Fast Ligand Exchange Reactions), Kazan: Kazan. Gos. Univ., 1985.
Zakharov, A.V. and Shtyrlin, V.G., Koord. Khim., 1989, vol. 15, no. 4, p. 435.
Aleksandrov, V.V., Kislotnost’ nevodnykh rastvorov (Acidity of Nonaqueous Solutions), Kharkov: Vishcha Shkola, 1982.
Author information
Authors and Affiliations
Additional information
Original Russian Text © G.V. Afanas’eva, T.I. Bychkova, V.G. Shtyrlin, A.R. Shakirova, A.V. Zakharov, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 5, pp. 794–802.
Rights and permissions
About this article
Cite this article
Afanas’eva, G.V., Bychkova, T.I., Shtyrlin, V.G. et al. Composition, stability, and structure of Cu(II), Ni(II), and Co(II) complexes with adipic acid dihydrazide in aqueous and aqueous-ethanol solutions. Russ J Gen Chem 76, 757–765 (2006). https://doi.org/10.1134/S1070363206050185
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1070363206050185