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Noncatalytic hydrophosphorylation and hydrothiophosphorylation of hydroxyaldehydes

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Abstract

Nucleophilic addition of secondary phosphone oxides and phosphine sulfides to 2-hydroxyacet-, 2-hydroxybenz-, and 3,4-dihydroxybenzaldehydes proceeds under mild conditions (48–50°C, THF) and allows tertiary phosphine oxides and phosphine sulfides with several hydroxyl groups to be prepared.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    N. I. Ivanova, N. K. Gusarova, N. A. Konovalova, L. M. Sinegovskaya, V. G. Samoilov, S. M. Markosyan, N. D. Avseenko, B. G. Sukhov & B. A. Trofimov

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  1. N. I. Ivanova
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  2. N. K. Gusarova
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  3. N. A. Konovalova
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  4. L. M. Sinegovskaya
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  5. V. G. Samoilov
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  6. S. M. Markosyan
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  7. N. D. Avseenko
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  8. B. G. Sukhov
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  9. B. A. Trofimov
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Additional information

Original Russian Text © N.I. Ivanova, N.K. Gusarova, N.A. Konovalova, L.M. Sinegovskaya, V.G. Samoilov, S.M. Markosyan, N.D. Avseenko, B.G. Sukhov, B.A. Trofimov, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 1, pp. 102–106.

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Ivanova, N.I., Gusarova, N.K., Konovalova, N.A. et al. Noncatalytic hydrophosphorylation and hydrothiophosphorylation of hydroxyaldehydes. Russ J Gen Chem 76, 98–102 (2006). https://doi.org/10.1134/S107036320601018X

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  • DOI: https://doi.org/10.1134/S107036320601018X

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