Skip to main content
SpringerLink
Log in

H NMR study of interparticle interactions in the system rare-earth element-acetic acid-diamagnetic salt

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Complexation of acetic acid in 5.0 M NaNO3 at 298 K with yttrium-group rare-earth ions (Dy3+, Er3+, Tm3+, Yb3+) in the absence and in the presence of Mg2+ ions was studied by 1H NMR spectroscopy in combination with mathematical simulation of complex equilibria. In the presence of Mg2+, the stability constants of monoacetate complexes of rare-earth ions decrease relative to the Mg-free systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Smith, R.M. and Martell, A.E., Critical Stability Constants, New York: Plenum, 1982, vol. 6, 2nd suppl., p. 528.

    Google Scholar 

  2. Perrin, D.D., IUPAC Chemical Data Ser. no. 22: Stability Constants of Metal-Ion Complexes, 2nd suppl., part B: Organic Ligands, Oxford: Pergamon, 1982.

    Google Scholar 

  3. NIST Standard Reference Database 46. Ver. 6.0, Martell, A.E. and Smith, R.M., Eds., Gaithersburg: National Inst. of Standards and Technology, 2001.

    Google Scholar 

  4. Deberdt, S., Castet, S., Dandurand, J.L., and Harrichoury, J.G., Chem. Geol., 2000, vol. 167, nos. 1–2, p. 75.

    CAS  Google Scholar 

  5. Partanen, J.I. and Juusola, P.M., Fluid Phase Equil., 2000, vol. 169, no. 2, p. 149.

    Article  CAS  Google Scholar 

  6. Pitzer, K.S., J. Phys. Chem., 1973, vol. 77, no. 2, p. 268.

    Article  CAS  Google Scholar 

  7. Scatchard, G., Equilibrium in Solutions, Cambridge: Harvard Univ. Press, 1976, p. 208.

    Google Scholar 

  8. Mironov, I.V., Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, 1981, issue 6, no. 3, p. 54.

    Google Scholar 

  9. Bromley, L.A., Am. Inst. Chem. Eng. J., 1973, vol. 19, no. 2, p. 313.

    CAS  Google Scholar 

  10. Helgeson, H.C. and Kirkham, D.H., Am. J. Sci., 1974, vol. 274, no. 10, p. 1199.

    CAS  Google Scholar 

  11. Wood, S.A., Wesolowski, D.J., and Palmer, D.A., Chem. Geol., 2000, vol. 167, nos. 1–2, p. 231.

    CAS  Google Scholar 

  12. Glasoe, P.K. and Long, F.A., J. Phys. Chem., 1960, vol. 64, no. 1, p. 188.

    CAS  Google Scholar 

  13. Sawyer, D.T. and Brannan, J.R., Inorg. Chem., 1966, vol. 5, no. 1, p. 65.

    Article  CAS  Google Scholar 

  14. Buikliskii, V.D. and Panyushkin, V.T., Zh. Obshch. Khim., 1987, vol. 57, no. 10, p. 2262.

    CAS  Google Scholar 

  15. Buikliskii, V.D., Panyushkin, V.T., and Soldatenko, I.A., Zh. Obshch. Khim., 1990, vol. 60, no. 11, p. 2413.

    CAS  Google Scholar 

  16. Vashchuk, A.V., Panyushkin, V.T., and Fedorenko, N.L., Zh. Obshch. Khim., 1994, vol. 64, no. 1, p. 119.

    CAS  Google Scholar 

  17. Panyushkin, V.T., Sukhno, I.V., and Vodopetova, N.L., Zh. Obshch. Khim., 2003, vol. 73, no. 4, p. 541.

    Google Scholar 

  18. Sal’nikov, Yu.I., Glebov, A.A., and Devyatov, F.V., Poliyadernye kompleksy v rastvorakh (Polynuclear Complexes in Solutions), Kazan: Kazan. Gos. Univ., 1989.

    Google Scholar 

  19. Millero, F.J., Geochim. Cosmochim. Acta, 1992, vol. 56, no. 8, p. 3123.

    Article  CAS  Google Scholar 

  20. Fein, J.B., Geochim. Cosmochim. Acta, 1991, vol. 55, no. 4, p. 955.

    Article  CAS  Google Scholar 

  21. Skipper, N.T., Neilson, G.W., and Cummings, S.C., J. Phys. Condens. Matter, 1989, vol. 1, no. 22, p. 3489.

    Article  CAS  Google Scholar 

  22. Luo Yu-Ran and Byrne, R.H., J. Solution Chem., 2001, vol. 30, no. 9, p. 837.

    Article  CAS  Google Scholar 

  23. Woolard, C.A., Computer Simulation of the Trace Metal Speciation in Seawater, PhD Thesis, Univ. Cape Town, 1995.

  24. May, P.M. and Murray, K., Talanta, 1993, vol. 40, no. 6, p. 819.

    Article  CAS  Google Scholar 

  25. Wanner, H. and Osthols, E., Standards and Conventions for TDB Publications, Issy-les-Moulineaux, 2000.

  26. Riddel, J.D., Lokwood, D.J., and Trich, D.E., Can. J. Chem., 1972, vol. 50, no. 21, p. 2951.

    Google Scholar 

  27. Vashchuk, A.V., Sukhno, I.V., and Panyushkin, V.T., Zh. Obshch. Khim., 1998, vol. 68, no. 12, p. 1941.

    Google Scholar 

  28. Vashchuk, A.V., Sukhno, I.V., and Panyushkin, V.T., Koord. Khim., 1998, vol. 24, no. 9, p. 719.

    Google Scholar 

  29. Vashchuk, A.V., Sukhno, I.V., and Panyushkin, V.T., Koord. Khim., 1999, vol. 25, no. 7, p. 556.

    Google Scholar 

  30. Panyushkin, V.T., Sukhno, I.V., and Arutunyan, I.V., J. Mol. Liq., 2001, vol. 92, no. 3, p. 235.

    Google Scholar 

  31. Choppin, G.R., J. Alloys Comp., 1997, vol. 249, nos. 1–2, p. 1.

    CAS  Google Scholar 

  32. Arutyunyan, M.M., Sukhno, I.V., Buz’ko, V.Yu., and Panyushkin, V.T., Koord. Khim., 2004, vol. 30, no. 2, p. 135.

    Google Scholar 

  33. Arutyunyan, M.M., Sukhno, I.V., Buz’ko, V.Yu., and Panyushkin, V.T., Zh. Fiz. Khim., 2003, vol. 77, no. 9, p. 1547.

    CAS  Google Scholar 

  34. Ohtaki, H., Monatsh. Chem., 2001, vol. 132, no. 11, p. 1237.

    CAS  Google Scholar 

  35. Choppin, G.R., J. Alloys Comp., 1997, vol. 249, nos. 1–2, p. 9.

    CAS  Google Scholar 

  36. Endom, L., Hertz, H.G., Thul, B., and Zeidler, M.D., Ber. Bunsenges. Phys. Chem., 1967, vol. 71, nos. 9–10, p. 1008.

    CAS  Google Scholar 

  37. Motekaitis, R.J. and Martell, A.E., The Determination and Use of Stability Constants, New York, VCH, 1988.

    Google Scholar 

  38. Gans, P. and O’sullivan, B., Talanta, 2000, vol. 51, no. 1, p. 33.

    Article  CAS  Google Scholar 

  39. Burai, L., Ren, J., Kovacs, Z., Brucher, Z., and Sherry, A.D., Inorg. Chem., 1998, vol. 37, no. 1, p. 69.

    Article  Google Scholar 

  40. Burai, L., Kiraly, R., Lazar, I., and Brucher, E., Eur. J. Inorg. Chem., 2001, no. 4, p. 813.

  41. Fife, T.H. and Bruice, T.C., J. Phys. Chem., 1961, vol. 65, no. 6, p. 1079.

    CAS  Google Scholar 

  42. Carvalho, R.A., Peters, J.A., and Geraldes, C.F.G.C., Inorg. Chim. Acta, 1997, vol. 262, no. 2, p. 167.

    Article  CAS  Google Scholar 

  43. Dagnall, S. and Hague, D., J. Chem. Soc., Faraday Trans., 1985, vol. 81, no. 9, p. 1483.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kuban State University, ul. Stavropol’skaya 149, Krasnodar, 350040, Russia

    I. V. Sukhno, V. Yu. Buz’ko & V. T. Panyushkin

Authors
  1. I. V. Sukhno
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Yu. Buz’ko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. T. Panyushkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © I.V. Sukhno, V.Yu. Buz’ko, V.T. Panyushkin, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 1, pp. 25–31.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sukhno, I.V., Buz’ko, V.Y. & Panyushkin, V.T. H NMR study of interparticle interactions in the system rare-earth element-acetic acid-diamagnetic salt. Russ J Gen Chem 76, 22–28 (2006). https://doi.org/10.1134/S1070363206010051

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363206010051

Keywords

Search

Navigation