Abstract
The enthalpies of mixing of aqueous solutions of copper(II) and nickel(II) nitrates with water-formamide mixtures were measured calorimetrically at 298.15 K in the entire composition range. The standard enthalpies of transfer of the electrolytes from water to water-formamide mixtures were calculated from these data. The shape of the isotherms of transfer of the electrolytes is discussed on the basis of the calculated enthalpies of transfer of individual ions and contributions to these quantities made by universal, chemical, and electrostatic interactions of ions with the solvents.
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References
Krestov, G.A., Vinogradov, V.I., Kessler, Yu.M., and Abrosimov, V.K., Sovremennye problemy khimii rastvorov (Modern Problems of Chemistry of Solutions), Moscow: Nauka, 1986.
Kessler, Yu.M., Zh. Fiz. Khim., 1975, vol. 49, no. 11, p. 2950.
Hayskens, F.I., J. Am. Chem. Soc., 1977, vol. 99, no. 10, p. 2579.
Korolev, V.P., Vandyshev, V.N., and Krestov, G.A., Zh. Obshch. Khim., 1987, vol. 57, no. 8, p. 1815.
Visser, C. and Somsen, G., J. Solution Chem., 1974, vol. 3, no. 11, p. 847.
Vandyshev, V.N., Cand. Sci. (Chem.) Dissertation, Ivanovo, 1988.
Krestov, G.A., Korolev, V.P., and Vandyshev, V.N., Dokl. Akad. Nauk SSSR, 1990, vol. 313, no. 3, p. 641.
Korolev, V.P., Zh. Obshch. Khim., 1998, vol. 68, no. 2, p. 188.
Bondi, F., J. Phys. Chem., 1964, vol. 68, no. 3, p. 441.
Bosch, E. and Roses, M., J. Chem. Soc., Faraday Trans., 1992, vol. 88, no. 24, p. 3541.
Mikheev, S.V., Cand. Sci. (Chem.) Dissertation, Ivanovo, 1995.
Levandowski, A., Electrochim. Acta, 1984, vol. 29, no. 4, p. 547.
Gabibulina, Kh.V., Boos, G.A., and Sal’nikov, Yu.I., Zh. Neorg. Khim., 1993, vol. 38, no. 6, p. 1036.
Vandyshev, V.N., Korolev, V.P., and Krestov, G.A., Zh. Neorg. Khim., 1991, vol. 36, no. 9, p. 2029.
Subbarangai, K., Monahara, M.N., and Subrahmanyam, S.V., Acustica, 1985, vol. 58, no. 2, p. 105.
Levandowski, A., Electrochim. Acta, 1985, vol. 30, no. 3, p. 311.
Manin, N.G., Baranov, D.V., and Korolev, V.P., Zh. Neorg. Khim., 2003, vol. 48, no. 2, p. 345.
Devyatov, F.V., Safina, V.F., Lazareva, L.G., and Sal’nikov, Yu.I., Zh. Neorg. Khim., 1993, vol. 38, no. 6, p. 1085.
Korolev, V.P., Batov, D.V., Vandyshev, V.N., and Krestov, G.A., Zh. Fiz. Khim., 1983, vol. 51, no. 1, p. 253.
Vandyshev, V.N. and Batov, D.V., Abstracts of Papers, Mezhdunarodnaya konferentsiya “Fizikokhimicheskii analiz zhidkofaznykh sistem” (Int. Conf. “Physicochemical Analysis of Liquid-Phase Systems”), Saratov, 2003, p. 71.
Weissberger, A. and Proskauer, E.S., Organic Solvents. Physical Properties and Methods of Purification, Riddick, J.A. and Toops, E.E., Eds., New York: Interscience, 1955.
Shormanov, V.A., Sharnin, V.A., and Ledenkov, S.F., Zh. Neorg. Khim., 1996, vol. 41, no. 5, p. 1817.
Zaichikov, A.N., Cand. Sci. (Chem.) Dissertation, Ivanovo, 1995.
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Original Russian Text © V.N. Vandyshev, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 1, pp. 19–24.
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Vandyshev, V.N. Thermochemical characteristics of transfer of copper(II) and nickel(II) nitrates from water to water-formamide mixtures. Russ J Gen Chem 76, 17–21 (2006). https://doi.org/10.1134/S107036320601004X
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DOI: https://doi.org/10.1134/S107036320601004X