Abstract
The intermediate and final products of the reactions of magnesium with diphenylantimony and diphenylbismuth chlorides were identified, and the formal kinetic relationships of the process were elucidated. The apparent equilibrium constants, enthalpies, and entropies of adsorption of the reagents on the metal surface, and also the rate constants and activation energies of the reactions in dimethylformamide-p-xylene mixture were determined. Probable schemes of magnesium oxidation with the organobismuth and organoantimony chlorides were considered.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Piskunov, A.V., Maslennikov, S.V., Spirina, I.V., and Maslennikov, V.P., Koord. Khim., 2002, vol. 28, no. 11, p. 861.
Herbstman, S., J. Org. Chem., 1964, vol. 29, no. 4, p. 986.
Brewning, H.J. and Severengiz, T., Z. Naturforsch. B, 1982, vol. 37, p. 345.
Wiberg, E. and Modritzer, K., Z. Naturforsch. B, 1957, vol. 12, p. 132.
Kocheshkov, K.A., Skoldinov, A.P., and Zemlyanskii, N.N., Metody elementoorganicheskoi khimii (Methods of Organometallic Chemistry. Antimony and Bismuth), Moscow: Nauka, 1976.
Charlot, G., Les methods de la chimie analytique. Analyse quantitative minerale, Paris: Masson, 1961, 4th ed.
Perel’man, V.I., Kratkii spravochnik khimika (Concise Chemist’s Handbook), Moscow: Khimiya, 1964.
Piskunov, A.V., Maslennikov, S.V., Spirina, I.V., Artemov, A.N., and Malysheva, E.V., Zh. Obshch. Khim., 2003, vol. 73, no. 7, p. 1114.
Cleg, W., Compton, N.A., Errington, R.J., Norman, N.C., Tucker, A.J., and Winter, M.J., J. Chem. Soc., Dalton Trans., 1988, no. 12, p. 2941.
Hayter, R.G., Inorg. Chem., 1963, vol. 2, no. 5, p. 1031.
Maslennikov, S.V., Malysheva, E.V., Spirina, I.V., and Artemov, A.N., Zh. Obshch. Khim., 2005, vol. 75, no. 4, p. 529.
Piskunov, A.V., Cand. Sci. (Chem.) Dissertation, Nizhni Novgorod, 2001.
Bremer, H. and Wendlandt, K.-P., Heterogene Katalyse: eine Einführung, Berlin: Akademie, 1978.
Maslennikov, S.V. and Spirina, I.V., Zh. Obshch. Khim., 1998, vol. 68, no. 2, p. 300.
Gordon, A.J. and Ford, R.A., The Chemist’s Companion, and References, New York: Wiley, 1972.
Zhukov, S.L., Lavrent’ev, I.P., and Nifontova, T.A., React. Kinet. Catal. Lett., 1977, vol. 7, no. 4, p. 405.
Author information
Authors and Affiliations
Additional information
Original Russian Text © S.V. Maslennikov, S.V. Klement’eva, Ya.V. Losev, I.V. Spirina, V.P. Maslennikov, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 1, pp. 3–6.
Rights and permissions
About this article
Cite this article
Maslennikov, S.V., Klement’eva, S.V., Losev, Y.V. et al. Oxidation of magnesium with diphenylbismuth and diphenylantimony chlorides in polar solvents. Russ J Gen Chem 76, 1–4 (2006). https://doi.org/10.1134/S1070363206010014
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1070363206010014