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Halide Complexes [(2-Br-5-MePy)2ZnX2] (X = Cl, Br): Structure and Noncovalent Interactions in the Crystal Structure

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Abstract

The heteroligand complexes [(2-Br-5-MePy)2ZnX2] (X = Cl (I), Br (II)) were prepared by the reaction of zinc(II) chloride or bromide with 2-bromo-5-methylpyridine and studied by X-ray diffraction (CCDC nos. 2204966 (I) and 2204967 (II)). The crystals of I and II contain Cl···Br and Br···Br halogen bonds, which connect the [MX2L2] moieties into supramolecular chains. The energies of these noncovalent interactions were estimated using quantum chemical calculations.

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ACKNOWLEDGMENTS

A.S. Novikov is grateful to the program of strategic academic leadership of the Peoples’ Friendship University of Russia.

Funding

This study was supported by the Ministry of Education and Science of the Russian Federation (structural characterization of samples, 121031700313-8).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. A. Vershinin & S. A. Adonin

  2. St. Petersburg State University, St. Petersburg, Russia

    A. S. Novikov

  3. Peoples’ Friendship University of Russia, Moscow, Russia

    A. S. Novikov

Authors
  1. M. A. Vershinin
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  2. A. S. Novikov
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  3. S. A. Adonin
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Correspondence to S. A. Adonin.

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Translated by Z. Svitanko

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Vershinin, M.A., Novikov, A.S. & Adonin, S.A. Halide Complexes [(2-Br-5-MePy)2ZnX2] (X = Cl, Br): Structure and Noncovalent Interactions in the Crystal Structure. Russ J Coord Chem 49, 294–298 (2023). https://doi.org/10.1134/S1070328423700574

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