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Tetraphenylphosphorus and Tetraphenylantimony (2-Carboxy)benzenesulfonates: Synthesis and Structures

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Abstract

The reactions of pentaphenylphosphorus and pentaphenylantimony with 2-sulfobenzoic acid in benzene afford tetraphenylphosphonium [Ph4P]+[OSO2C6H4(COOH-2)]− (I) and tetraphenylstibonium [Ph4Sb]+[OSO2C6H4(COOH-2)]− (II) (2-carboxy)benzenesulfonates in the yield up to 90%. Compounds I and II are also synthesized from tetraphenylphosphonium and tetraphenylstibonium chlorides and 2-sulfobenzoic acid in water in the yield up to 89%. The complexes are characterized by X-ray diffraction (XRD) (CIF files CCDC nos. 2144288 (I) and 2123516 (II)) and IR spectroscopy.

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Authors and Affiliations

  1. South Ural State University (National Research University), Chelyabinsk, Russia

    A. N. Efremov & V. V. Sharutin

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  1. A. N. Efremov
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  2. V. V. Sharutin
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Correspondence to V. V. Sharutin.

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Translated by E. Yablonskaya

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Efremov, A.N., Sharutin, V.V. Tetraphenylphosphorus and Tetraphenylantimony (2-Carboxy)benzenesulfonates: Synthesis and Structures. Russ J Coord Chem 49, 318–323 (2023). https://doi.org/10.1134/S1070328423700549

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  • DOI: https://doi.org/10.1134/S1070328423700549

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