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Synthesis and Structure of Tetraphenylstibonium Organosulfonates Ph4SbOSO2R, R = C10H15O, C10H4(OH-1)(NO2)2-2,4, C10H7-1, C6H4(COOH-2)

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Abstract

The reaction of equimolar amounts of pentaphenylantimony with camphor-10-sulfonic, 2,4-dinitro-1-naphthol-7-sulfonic (flavianic), 1-naphthalenesulfonic, and 2-sulfobenzoic acids in benzene resulted in the synthesis of tetraphenylstibonium organosulfonates Ph4SbOSO2C10H15O∙H2O (I), Ph4SbOSO2C10H4(OH-1)(NO2)2-2,4∙PhH (II), Ph4SbOSO2(C10H7-1)∙H2O (III), and Ph4SbOSO2C6H4(COOH-2) (IV). According to X-ray diffraction data (CCDC no. 2119791 (I), 2121381 (II), 2116582 (III), and 2123516 (IV), the crystal of I contains trigonal-bipyramidal sulfonate molecules (the axial Sb−C and Sb−O bond lengths are 2.130(3) and 2.565(2) Å, respectively) and hydration water molecules, which form a centrosymmetric eight-membered ring (the S=O∙∙∙H−O−H∙∙∙O=S distances are 2.06 and 2.21 Å). In the molecules of II, the metal atom geometry is a distorted trigonal bipyramid (the axial Sb−C and Sb−O bonds are 2.133(2) and 2.643(3) Å, respectively). The Sb−O distance (2.842(3) Å) is longer in III than in I or II; the hydration water molecules form centrosymmetric twelve-membered rings with the anions (the S=O∙∙∙H−O−H∙∙∙O=S distances are 2.02 and 2.05 Å). Meanwhile, the crystal of compound IV consists of tetrahedral tetraphenylstibonium cations and (2-carboxy)benzenesulfonate anions with the intramolecular O−H∙∙∙O=S hydrogen bond (1.75 Å).

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Authors and Affiliations

  1. South Ural State University (National Research University), Chelyabinsk, Russia

    V. S. Senchurin, V. V. Sharutin, O. K. Sharutina & V. V. Krasnoselskaya

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  1. V. S. Senchurin
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  2. V. V. Sharutin
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  3. O. K. Sharutina
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  4. V. V. Krasnoselskaya
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Translated by Z. Svitanko

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Senchurin, V.S., Sharutin, V.V., Sharutina, O.K. et al. Synthesis and Structure of Tetraphenylstibonium Organosulfonates Ph4SbOSO2R, R = C10H15O, C10H4(OH-1)(NO2)2-2,4, C10H7-1, C6H4(COOH-2). Russ J Coord Chem 49, 311–317 (2023). https://doi.org/10.1134/S1070328423700513

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