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A Surprising Example of Crystal Structure Retention for 3,5-Di-(tert-butyl)-2-hydroxyazobenzene Ligand during the Formation of Ni(II) and Pd(II) Complexes

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Abstract

The structures of 3,5-di-(tert-butyl)-2-hydroxyazobenzene (L) in the free state and in complexes with Ni2+ (I) and Pd2+ (II) cations are studied by X-ray diffraction (XRD). The same space group R\(\bar {3}\)с with close unit cell parameters, the same crystal structure motif, and unusual conformations of the cupola-shaped coordination polyhedra of complexes I and II are revealed by XRD for ligand L. In complexes I and II based on this compound as the ligand, the coordinating atoms form trans-planar coordination nodes.

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REFERENCES

  1. Kogan, V.A., Kharabaev, N.N., Osipov, O.A., and Yurchenko, E.N., Zh. Obshch. Khim., 1975, vol. 45, p. 362.

    CAS  Google Scholar 

  2. Kogan, V.A., Kharabaev, N.N., Osipov, O.A., and Kochin, S.G., Zh. Strukt. Khim., 1981, vol. 22, no. 1, p. 126.

    CAS  Google Scholar 

  3. D’yachenko, O.A., Atovmyan, L.O., Aldoshin, S.M., and Tkachev, V.V., Zh. Strukt. Khim., 1978, vol. 19, no. 5, p. 829.

    Google Scholar 

  4. Kogan, V.A., Kochin, S.G., Antsyshkina, A.S., et al., Mendeleev Commun., 1997, vol. 7, no. 6, p. 239.

    Article  Google Scholar 

  5. Aldoshin, C.M., Alekseenko V.A., Atovmyan L.O. et al., Koord. Khim., 1975, vol. 10, p. 1075.

    Google Scholar 

  6. Burlov, A.S., Uraev, A.I., Lysenko, K.A., et al., Russ. J. Inorg. Chem., 2015, vol. 60, p. 1481. https://doi.org/10.1134/S0036023615120062

    Article  CAS  Google Scholar 

  7. Kogan, V.A., Lyubchenko, S.N., Shcherbakov, I.N., et al., Russ. J. Coord. Chem., 2005, vol. 31, no. 8, p. 533. https://doi.org/10.1007/s11173-005-0132-0

    Article  CAS  Google Scholar 

  8. Tkachev, V.V., Bozhenko, K.V., Utenyshev, A.N., et al., Russ. Chem. Bull., Int. Ed., 2021, vol. 70, no. 5, p. 847.

    CAS  Google Scholar 

  9. Kostic, M.N. and Dutca, L.M., Comprehensive Coordination Chemistry II, McCleverty, Y.A. and Meyer, T.Y., Eds., Amsterdam: Elesevier, 2003, p. 556.

  10. Ana, S.D., Ferreira, M., Fernanda, N.N., et al., Inorg. Chim. Acta, 2013, vol. 395, p. 169.

    Article  Google Scholar 

  11. Sheldrick, G.M., The SHELX-97. Manual, Göttingen: Univ. of Göttingen, 1997.

  12. License to Use Agreement, Gaussian, Inc., 340 Quinnipiac Street, Building 40, Wallingford, CT 06492.

  13. Kresse, G. and Furthmuller, J., Phys. Rev. B, 1996, vol. 54, p. 11169.

    Article  CAS  Google Scholar 

  14. Kresse, G. and Joubert, D., Phys. Rev. B, 1999, vol. 59, p. 1758. https://doi.org/10.1103/PhysRevB.59.1758

    Article  CAS  Google Scholar 

  15. Marten, J., Seichter, W., and Weber, E., Z. Anorg. Allg. Chem., 2005, vol. 631, p. 869.

    Article  CAS  Google Scholar 

  16. Kurbatov, V.P., Antsyshkina, A.S., Kukharicheva, E.S., and Garnovsky, A.D., Russ. J. Inorg. Chem., 1996, vol. 41, no. 8, p. 1259.

    Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to workers of the Chair of Physical and Colloidal Chemistry named after Prof. V.A. Kogan (Southern Federal University) for kindly presented crystals for XRD and for interest in the work.

Funding

This work was supported by state assignment of the Institute of Problems of Chemical Physics of the Russian Academy of Sciences (state registration, project no. AAAA-A19-119092390076-7).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    S. M. Aldoshin, V. V. Tkachev, A. N. Utenyshev & K. V. Bozhenko

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  1. S. M. Aldoshin
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  2. V. V. Tkachev
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  3. A. N. Utenyshev
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  4. K. V. Bozhenko
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Correspondence to K. V. Bozhenko.

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Translated by E. Yablonskaya

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Aldoshin, S.M., Tkachev, V.V., Utenyshev, A.N. et al. A Surprising Example of Crystal Structure Retention for 3,5-Di-(tert-butyl)-2-hydroxyazobenzene Ligand during the Formation of Ni(II) and Pd(II) Complexes. Russ J Coord Chem 49, 304–310 (2023). https://doi.org/10.1134/S1070328423700495

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