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The First Perylene Complexes of Neodymium and Dysprosium

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Abstract

Neodymium and dysprosium perylene complexes LnI(Per)(DME)2⋅Per (Ln = Nd, Dy) were obtained for the first time by the reaction of the Ln diiodides with perylene in dimethoxyethane. The structure of dysprosium complex was established by X-ray diffraction (CCDC no. 2184200). Experimental–theoretical electron density analysis was performed to specify the type of coordination between the dysprosium cation and perylene in DyI(Per)(DME)2⋅Per. Despite the identical composition, the Nd and Dy complexes have different structures, which is reflected in their luminescence properties.

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ACKNOWLEDGMENTS

This study was performed using the equipment of the center for collective use “Analytical Center of the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences” supported by the grant “Provision of the Development of the Material and Technical Infrastructure of Centers for Collective Use” (unique identifier RF–2296.61321X0017, contract number 075-15-2021-670).

Funding

This study was supported by the Russian Science Foundation (grant no. 22-23-00547).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    T. V. Balashova, S. K. Polyakova, A. A. Fagin, V. A. Ilichev, K. A. Kozhanov, E. V. Baranov, G. K. Fukin & M. N. Bochkarev

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  1. T. V. Balashova
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  2. S. K. Polyakova
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Correspondence to T. V. Balashova.

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Translated by Z. Svitanko

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Balashova, T.V., Polyakova, S.K., Fagin, A.A. et al. The First Perylene Complexes of Neodymium and Dysprosium. Russ J Coord Chem 49, 257–266 (2023). https://doi.org/10.1134/S1070328423700471

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  • DOI: https://doi.org/10.1134/S1070328423700471

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