Skip to main content
SpringerLink
Log in

Effect of Substituents in the Pentafluorobenzoate and 2,3,4,5- and 2,3,5,6-Tetrafluorobenzoate Anions on the Structure of Cadmium Complexes

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

New cadmium 2,3,4,5-tetrafluorobenzoate (6HTfb) and 2,3,5,6-tetrafluorobenzoate (4Htfb) complexes, [Cd(6HTfb)(H2O)3]n·(6HTfb)·2nH2O (I), [Cd3(Phen)2(6HTfb)6] (II, Phen = 1,10-phenanthroline), [Cd2(Phen)2(4Htfb)4]n·2nH2O (III), and [Cd(Phen)2(4Htfb)2] (IV), were synthesized. Analysis of the obtained results and published data demonstrated that a decrease in the number of fluorine substituents is unfavorable for the formation of coordination polymers comprising stacked alternating fluorinated and non-fluorinated aromatic moieties. In the case of 2,4,5-trifluorobenzoate complex, a typical trivial structure of the binuclear cadmium complex with ligand-shielded metal core is formed. The synthesis of 2,3,4,5- and 2,3,5,6-tetrafluorobenzoate complexes produced an intermediate situation and demonstrated that the structure of complex formation products is affected by not only the number, but also the positions of fluorine substituents. Using quantum chemical calculations, it was shown that the formation of coordination polymers requires a molecular precursor with a Chinese lantern structure stable in solutions, while the formation of unusual flattened binuclear complexes with additionally coordinated water molecules requires doubly bridged binuclear complexes able to switch to a conformation with exposed coordinatively unsaturated metal centers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

REFERENCES

  1. Saxena, P. and Thirupathi, N., Polyhedron, 2015, vol. 98, no. 1, p. 238.

    Article  CAS  Google Scholar 

  2. Pryma, O.V., Petrusenko, S.R., Kokozay, V.N., et al., Inorg. Chem. Commun., 2003, vol. 6, no. 7, p. 896.

    Article  CAS  Google Scholar 

  3. Zhao, Q.-H., Ma, Y.-P., Wang, Q.-H., and Fang, R.-B., Chin. J. Struct. Chem., 2002, vol. 21, p. 513.

    CAS  Google Scholar 

  4. Shmelev, M.A., Kuznetsova, G.N., Gogoleva, N.V., et al., Russ. Chem. Bull., 2021, vol. 70, no. 5, p. 830.

    Article  CAS  Google Scholar 

  5. Shmelev, M.A., Chistyakov, A.S., Razgonyaeva, G.A., et al., Crystals, 2022, vol. 12, p. 508.

    Article  CAS  Google Scholar 

  6. Yang, Y.-Q., Li, C.-H., Li, W., and Kuang, Y.-F., Chin. J. Inorg. Chem., 2009, vol. 25, p. 1120.

    CAS  Google Scholar 

  7. Nie, J.-J., Pan, T.-T., Su, J.-R., and Xu, D.-J., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2010, vol. 66, p. m760.

    Article  CAS  PubMed  Google Scholar 

  8. Gogoleva, N.V., Shmelev, M.A., Evstifeev, I.S., et al., Russ. Chem. Bull., 2016, vol. 65, p. 181.

    Article  CAS  Google Scholar 

  9. Li, W., Li, C.-H., Yang, Y.-Q., and Li, Y.-L., Chin. J. Inorg. Chem., 2010, vol. 26, p. 166.

    CAS  Google Scholar 

  10. Kuznetsova, G.N., Yambulatov, D.S., Kiskin, M.A., et al., Russ. J. Coord. Chem., 2020, vol. 46, p. 553. https://doi.org/10.1134/S1070328420080047

    Article  CAS  Google Scholar 

  11. Itoh, T., Kondo, M., Kanaike, M., and Masaoka, S., CrystEngComm, 2013, vol. 15, p. 6122.

    Article  CAS  Google Scholar 

  12. Cockcroft, J.K., Rosu-Finsen, A., Fitch, A.N., and Williams, J.H., CrystEngComm, 2018, vol. 20, p. 6677.

    Article  CAS  Google Scholar 

  13. Lee, G.Y., Hu, E., Rheingold, A.L., Houk, K.N., and Sletten, E.M., Org. Chem., 2021, vol. 86, p. 8425.

    Article  CAS  Google Scholar 

  14. Shmelev, M.A., Kuznetsova, G.N., Dolgushin, F.M., et al, Russ. J. Coord. Chem., 2021, vol. 47, p. 127. https://doi.org/10.1134/S1070328421020068

    Article  CAS  Google Scholar 

  15. Shmelev, M.A., Voronina, J.K., Evtyukhin, M.A., et al., Inorganics, 2022, vol. 10, p. 194.

    Article  CAS  Google Scholar 

  16. Shmelev, M.A., Kiskin, M.A., Voronina, J.K., et al., Materials, 2020, vol. 13, no. 24, p. 5689.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  17. Voronina, J.K., Yambulatov, D.S., Chistyakov, A.S., et al., Crystals, 2023, vol. 13, p. 678.

    Article  CAS  Google Scholar 

  18. Li, J.-X. and Du, Z.-X., J. Cluster Sci., 2020, vol. 31, p. 507.

    Article  CAS  Google Scholar 

  19. Wu, W.P., Wang, J., Lu, L., Xie, B., Wu, Y., and Kumar, A., Russ. J. Coord. Chem., 2016, vol. 42, p. 71.

    Article  CAS  Google Scholar 

  20. Corradi, A.B., Menabue, L., Saladini, M., Sola, M., and Battaglia, L.P., Dalton Trans., 1992, p. 2623.

  21. Nikolaevskii, S.A., Evstifeev, I.S., and Kiskin, M.A., et al., Polyhedron, 2018, vol. 152, p. 61.

    Article  CAS  Google Scholar 

  22. Shmelev, M.A., Gogoleva, N.V., Dolgushin, F.M., et al., Russ. J. Coord. Chem., 2020, vol. 46, no. 7, p. 493. https://doi.org/10.1134/S1070328420070076

    Article  Google Scholar 

  23. Yang, Y.-Q., Li, C.-H., Li, W., and Kuang, Y.-F., Chin. J. Inorg. Chem., 2010, vol. 26, p. 1890.

    CAS  Google Scholar 

  24. Zha, M.-Q., Li, X., and Bing, Y., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2010, vol. 67, p. m8.

    Article  PubMed  Google Scholar 

  25. SMART (control) and SAINT (integration). Software. Version 5.0, Madison: Bruker AXS Inc., 1997.

  26. Sheldrick, G.M., SADABS, Madison: Bruker AXS Inc., 1997.

    Google Scholar 

  27. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  28. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystallogr., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  29. Casanova, D., Llunell, M., Alemany, P., and Alvarez, S., Chem.-Eur. J., 2005, vol. 11, p. 1479.

    Article  CAS  PubMed  Google Scholar 

  30. Frisch, M.J., Trucks, G.W., Schlegel, H.B., et al., Gaussian 16. Revision A. 03, Wallingford: Gaussian, 2016.

    Google Scholar 

  31. Kohn, W. and Sham, L.J., Phys. Rev. A, 1965, vol. 140, p. 1133.

    Article  Google Scholar 

  32. Becke, A.D., J. Chem. Phys., 1993, vol. 98, p. 5648.

    Article  CAS  Google Scholar 

  33. Nikolaevskii, S.A., Kiskin, M.A., Starikova, A.A., et al., Russ. Chem. Bull., 2016, vol. 65, p. 2812.

    Article  CAS  Google Scholar 

  34. Nikolaevskii, S.A., Kiskin, M.A., Starikov, A.G., et al., Russ. J. Coord. Chem., 2019, vol. 45, no. 4, p. 273. https://doi.org/10.1134/S1070328419040067

    Article  CAS  Google Scholar 

  35. Gogoleva, N.V., Shmelev, M.A., Kiskin, M.A., et al., Russ. J. Coord. Chem., 2021, vol. 47, no. 4, p. 261. https://doi.org/10.1134/S1070328421040035

    Article  CAS  Google Scholar 

  36. Grimme, S., Ehrlich, S., and Goerigk, L.L., J. Comput. Chem., 2011, vol. 32, p. 1456.

    Article  CAS  PubMed  Google Scholar 

  37. Yanai, T., Tew, D., and Handy, N., Chem. Phys. Lett., 2004, vol. 393, p. 51.

    Article  CAS  Google Scholar 

  38. Chemcraft—Graphical Software for Visualization of Quantum Chemistry Computations. Version 1.8. Build 682, https://www.chemcraftprog.com.

  39. Ge, C.-H., Zhang, R., Fan, P., Zhang, X.-D., et al., Chin. Chem. Lett., 2013, vol. 24, p. 73.

    Article  CAS  Google Scholar 

  40. Lou, Q.-Z., Z. Kristallogr.-New Cryst. Struct., 2007, vol. 222, p. 105.

    Article  CAS  Google Scholar 

  41. Shmelev, M.A., Gogoleva, N.V., Kuznetsova, G.N., et al., Russ. J. Coord. Chem., 2020, vol. 46, no. 8, p. 557. https://doi.org/10.31857/S0132344X2008006X

    Article  CAS  Google Scholar 

  42. Dankhar, S.S. and Nagaraja, C.M., J. Solid State Chem., 2020, vol. 290, p. 121560.

    Article  Google Scholar 

  43. Wang, X.L., Zhang, J.X., Liu, G.C., et al., Russ. J. Coord. Chem., 2010, vol. 36, p. 662.

    Article  CAS  Google Scholar 

  44. Bu, X.-H., Tong, M.-L., Li, J.-R., et al., Cryst. Eng. Comm., 2005, vol. 7, p. 411.

    Article  CAS  Google Scholar 

  45. Clegg, W., Little, I.R., and Straughan, B.P., Inorg. Chem., 1988, vol. 27, p. 1916.

    Article  CAS  Google Scholar 

  46. Clegg, W., Harbron, D.R., and Straughan, B.P., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1991, vol. 47, p. 267.

    Article  Google Scholar 

  47. Escobedo-Martinez, C., Lozada, M.C., and Gnecco, D., J. Chem. Cryst., 2012, vol. 42, p. 794.

    Article  CAS  Google Scholar 

  48. Pramanik, A., Fronczek, F.R., Venkatraman, R., and Hossain, M.A., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2013, vol. 69, p. m643.

    Article  CAS  PubMed  Google Scholar 

  49. Necefoglu, H., Clegg, W., and Scott, A.J., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2002, vol. 58, p. m123.

    Article  CAS  Google Scholar 

  50. Jin, Z.-N. and Zhang, B.-S., Z.Kristallogr.-New Cryst. Struct., 2018, vol. 233, p. 179.

    Article  CAS  Google Scholar 

  51. Carballo, R., Covelo, B., Fernandez-Hermida, N., et al., J. Chem. Cryst., 2011, vol. 41, p. 1949.

    Article  CAS  Google Scholar 

  52. Tunsrichon, S., Sukpattanacharoen, C., Escudero, D., et al., Inorg. Chem., 2020, vol. 59, p. 6176.

    Article  CAS  PubMed  Google Scholar 

  53. Carballo, R., Covelo, B., Garcia-Martinez, E., et al., Appl. Organomet. Chem., 2004, vol. 18, p. 201.

    Article  CAS  Google Scholar 

  54. Sen, S., Saha, M.K., Kundu, P., et al., Inorg. Chim. Acta, 1999, vol. 288, p. 118.

    Article  CAS  Google Scholar 

  55. Roy, S., Bauza, A., Frontera, A., et al., CrystEngComm, 2015, vol. 17, p. 3912.

    Article  CAS  Google Scholar 

  56. Bai, H., Gao, H., and Hu, M., Adv. Mater. Res., 2014, vol. 997, p. 140.

    Article  CAS  Google Scholar 

  57. Li, W., Li, C.-H., Yang, Y.-Q., and Li, D.-P., Chin. J. Inorg. Chem., 2008, vol. 24, p. 2060.

    CAS  Google Scholar 

  58. Li, W., Li, C.-H., Yang, Y.-Q., et al., Chin. J. Inorg. Chem., 2007, vol. 23, p. 2013.

    CAS  Google Scholar 

  59. Li, W.-W., Bing, Y., Zha, M.-Q., et al., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2011, vol. 67, p. m1464.

    Article  CAS  PubMed  Google Scholar 

  60. Bing, Y., Li, X., Zha, M.-Q., and Wang, D.-J., Nano-Met. Chem., 2011, vol. 41, p. 798.

    CAS  Google Scholar 

  61. Zha, M.-Q., Li, X., and Bing, Y., J. Coord. Chem., 2011, vol. 64, p. 473.

    Article  CAS  Google Scholar 

  62. Pruchnik, F.P., Dawid, U., and Kochel, A., Polyhedron, 2006, vol. 25, p. 3647.

    Article  CAS  Google Scholar 

  63. Liu, C.-S., Sanudo, E.C., Yan, L.-F., et al., Transition Met. Chem., 2009, vol. 34, p. 51.

    Google Scholar 

  64. Song, W.-D., Yan, J.-B., and Hao, X.-M., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2008, vol. 64, p. m919.

    Article  CAS  PubMed  Google Scholar 

  65. Liu, G.-C., Qu, Y., Wang, X.-L., Zhang, J.-W., et al., Z. Anorg. Allg. Chem., 2014, vol. 640, p. 1696.

    Article  CAS  Google Scholar 

  66. Feng, S., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2008, vol. 64, p. m817.

    Article  CAS  PubMed  Google Scholar 

  67. Uvarova, M.A., Kushan, E.V., Andreev, M.V., et al., Russ. J. Inorg. Chem., 2012, vol. 57, p. 1314.

    Google Scholar 

  68. Gomez, V. and Corbella, M., Eur. J. Inorg. Chem., 2009, p. 4471.

  69. Kruszynski, R., Malinowska, A., Czakis-Sulikow-ska, D., and Lamparska, A., J. Coord. Chem., 2009, vol. 62, p. 911.

    Article  CAS  Google Scholar 

  70. Shao, C.-Y., Song, S., Song, M., et al., Chin. Chem. Res., 2011, vol. 22, p. 29.

    Article  CAS  Google Scholar 

  71. Deng, Z.-P., Gao, S., Huo, L.-H., and Zhao, H., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2007, vol. 63, p. m2694.

    Article  CAS  Google Scholar 

  72. Li Zuo, Li Zuohong, Yang Yingqun, Chen Zhimin, and Wang Ying, Chin. J. Inorg. Chem., 2008, vol. 24, p. 1360.

  73. Yang, Y.-Q., Li, C.-H., Li, W., et al., Chin. J. Struct. Chem., 2006, vol. 25, p. 1409.

    CAS  Google Scholar 

  74. Tabrizi, L., McArdle, P., Ektefan, M., and Chiniforoshan, H., Inorg. Chim. Acta, 2016, vol. 439, p. 138.

    Article  CAS  Google Scholar 

  75. Ge, C., Zhang, X., Yin, J., and Zhang, R., Chin. J. Chem., 2010, vol. 28, p. 2083.

    Article  CAS  Google Scholar 

  76. Torres, J.F., Bello-Vieda, N.J., Macias, M.A., et al., Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 2020, vol. 76, p. 166.

    Article  CAS  Google Scholar 

  77. Baur, A., Bustin, K.A., Aguilera, E., et al., Org. Chem. Front., 2017, vol. 4, p. 519.

    Article  CAS  Google Scholar 

  78. Gogoleva, N.V., Shmelev, M.A., Kiskin, M.A., et al., Russ. Chem. Bull., 2016, vol. 65, p. 1198.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

Single crystal and powder X-ray diffraction studies and IR spectroscopy and elemental analysis of complexes were performed using research equipment of the Center for Collective Use of Physical Investigation Methods of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, within the state assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of basic scientific research.

Funding

Complexes I and III were synthesized and studied under the Russian Federation Presidential grant MK-94.2022.1.3; complexes II and IV were synthesized and studied within the state assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of basic scientific research.

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. A. Shmelev, G. A. Razgonyaeva, D. S. Yambulatov, A. A. Sidorov & I. L. Eremenko

  2. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    A. G. Starikov

Authors
  1. M. A. Shmelev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. A. Razgonyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. S. Yambulatov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. G. Starikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Sidorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. L. Eremenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Sidorov.

Ethics declarations

The authors of this work declare that they have no conflicts of interest.

Additional information

Translated by Z. Svitanko

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shmelev, M.A., Razgonyaeva, G.A., Yambulatov, D.S. et al. Effect of Substituents in the Pentafluorobenzoate and 2,3,4,5- and 2,3,5,6-Tetrafluorobenzoate Anions on the Structure of Cadmium Complexes. Russ J Coord Chem 50, 179–194 (2024). https://doi.org/10.1134/S1070328423601486

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328423601486

Keywords:

Search

Navigation