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Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

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Abstract

The Сd(II) complexes with redox amphoteric 2,6-di-(tert-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L1 and L2 (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the 1Н, 13С, and 113Cd NMR spectroscopy (for complexes I and III) and IR spectroscopy data.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation (state assignment in the sphere of scientific activity, project no. FENW-2023-0017).

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, P. A. Knyazev, G. S. Borodkin & V. I. Minkin

  2. Moscow State University, Moscow, Russia

    K. A. Lysenko

Authors
  1. E. P. Ivakhnenko
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  2. Yu. G. Vitkovskaya
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  3. N. I. Merezhko
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  4. P. A. Knyazev
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  5. G. S. Borodkin
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  6. K. A. Lysenko
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  7. V. I. Minkin
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Correspondence to E. P. Ivakhnenko.

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Translated by E. Yablonskaya

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Ivakhnenko, E.P., Vitkovskaya, Y.G., Merezhko, N.I. et al. Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures. Russ J Coord Chem 50, 171–178 (2024). https://doi.org/10.1134/S1070328423601309

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  • DOI: https://doi.org/10.1134/S1070328423601309

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