Abstract
The reaction of aluminum bis-formate acenaphthene-1,2-diimine complex [(ArBIG-bian)Al(μ-OC(H)O)2Li(Thf)2] (I) (ArBIG-bian = 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene), prepared by binding carbon dioxide by aluminum diimine hydride [(ArBIG-bian)Al(H)2]–[Li(Thf)4]+, with borane dimethyl sulfide and ammonia was studied. The reaction of I with BH3∙SMe2 (1 : 1) in toluene affords the product of hydroboration of one formate group [(ArBIG-bian)Al(μ-OC(H)O)(OB(H)OCH3)Li(Thf)]2 (II), while the reaction of I with BH3∙SMe2 (1 : 2) is accompanied by reduction of both formate groups and gives complex [(ArBIG-bian)Al(OBOCH3)2OLi2(Thf)2BH4]2 (III), methoxyboroxine (CH3OBO)3 and, presumably, compound [(ArBIG-bian)AlOCH3]. The reaction of I with one equivalent of ammonia in THF gives adduct [(ArBIG-bian)Al(NH3)(μ-OC(H)O)2Li(Thf)2] (IV), in which ammonia is coordinated to the aluminum atom, while the key bonds in I have not undergone ammonolysis. Compounds II–IV were characterized by IR and NMR spectroscopy, elemental analysis, and X-ray diffraction (CCDC no. 2255017 (II), 2255018 (III), 2255019 (IV)).
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Funding
This study was supported by the Russian Science Foundation no. 20-13-00052 (https://rscf.ru/project/20-13-00052/) and performed using research equipment of the Center for Collective Use “Analytical Center of the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences” supported by the grant “Provision of the Development of Material and Technical Infrastructure of Centers for Collective Use of Research Equipment” (unique identifier RF–2296.61321X0017, agreement number 075-15-2021-670).
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Translated by Z. Svitanko
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Moskalev, M.V., Skatova, A.A., Bazanov, A.A. et al. Reactions of Carbon Dioxide Bound to Aluminum Diimine Hydride with Borane Dimethyl Sulfide and Ammonia. Russ J Coord Chem 50, 118–129 (2024). https://doi.org/10.1134/S1070328423600936
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DOI: https://doi.org/10.1134/S1070328423600936