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Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure

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Abstract

The multicomponent chemical reactions of Fe(SO4)∙7H2O, Li(Рiv), K(Рiv) (Рiv is pivalate anion), and heterocyclic N-donor ligands (pyridine (Рy), 1,10-phenanthroline (Рhen)) in anhydrous acetonitrile under an inert atmosphere afford new heterometallic tetranuclear complexes [\({\text{Fe}}_{2}^{{{\text{II}}}}\)Li2(Рiv)6(Рy)4] (I) and [\({\text{Fe}}_{2}^{{{\text{II}}}}\)Li2(Рiv)6(Рhen)2] (II) in which all carboxylate anions act as bridging ligands. The molecular and crystal structures of the compounds are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2220576 (I) and 2220577 (II·2CH3CN). In the studied complexes, the iron(II) atoms exist in the distorted octahedral ligand environment.

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ACKNOWLEDGMENTS

XRD, elemental analysis, and IR spectroscopy were carried out using the equipment of the Joint Research Center of Physical Methods of Research at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences).

Funding

This work was supported by the Russian Science Foundation, project no. 19-13-00436-P.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    D. S. Yambulatov, J. K. Voronina, S. A. Nikolaevskii, A. I. Poddel’skii, M. A. Kiskin & I. L. Eremenko

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  1. D. S. Yambulatov
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  2. J. K. Voronina
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  3. S. A. Nikolaevskii
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Correspondence to S. A. Nikolaevskii.

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Translated by E. Yablonskaya

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Yambulatov, D.S., Voronina, J.K., Nikolaevskii, S.A. et al. Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure. Russ J Coord Chem 49, 479–485 (2023). https://doi.org/10.1134/S1070328423600250

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