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Heteroleptic Metal-Organic Frameworks of Lanthanides (Lа, Ce, and Ho) Based on Ligands of the Anilate Type and Dicarboxylic Acids

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Abstract

New heteroleptic metal-organic frameworks of lanthanides, units of which contain anionic organic ligands of two types, are prepared by the solvothermal synthesis in N,N-dimethylformamide (DMF). The cross-linked coordination polymer [Ho2(CA)2(Bdc)·4DMF] (I) and two scaffold derivatives [La2(pQ)2(Bpdc)·4DMF] (II) and [Ce2(CA)(Bdc)2·4DMF]·2DMF (III·2DMF), where CA is chloranilic acid dianion, pQ is 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion, Bdc is terephthalic acid dianion, and Bpdc is 4,4'-biphenyldicarboxylic acid dianion, are synthesized. The structures of compounds I, II, and III·2DMF are studied by X-ray diffraction (XRD) (CIF file CCDC nos. 2212230, 2212231, and 2212232, respectively).

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ACKNOWLEDGMENTS

The work was carried out using the equipment of the Center for Collective Use “Analytical Center of Institute of Organometallic Chemistry of Russian Academy of Sciences” and supported by the project “Provision of Development of Material Technical Infrastructure of Centers for Collective Use of Scientific Equipment” (unique identifier RF–2296.61321X0017, agreement no. 075-15-2021-670).

Funding

This work was supported by the Russian Science Foundation, project no. 22-23-00750.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    O. Yu. Trofimova, A. V. Maleeva, K. V. Arsen’eva, A. V. Klimashevskaya, A. V. Cherkasov & A. V. Piskunov

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  1. O. Yu. Trofimova
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  2. A. V. Maleeva
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  3. K. V. Arsen’eva
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  4. A. V. Klimashevskaya
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  5. A. V. Cherkasov
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  6. A. V. Piskunov
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Correspondence to A. V. Piskunov.

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Translated by E. Yablonskaya

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Trofimova, O.Y., Maleeva, A.V., Arsen’eva, K.V. et al. Heteroleptic Metal-Organic Frameworks of Lanthanides (Lа, Ce, and Ho) Based on Ligands of the Anilate Type and Dicarboxylic Acids. Russ J Coord Chem 49, 276–285 (2023). https://doi.org/10.1134/S1070328423600183

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